Self‐Assembly of a Semiconductive and Photoactive Heterobimetallic Metal–Organic Capsule
We report the synthesis of a novel metal–organic capsule constructed from six pyrogallol[4]arene macrocycles, which are switched together by 16 FeIII and 16 CoII ions. This supramolecular structure is the first instance of a spheroidal heterometallic nanocage assembled through a one‐step metal–ligan...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2021-05, Vol.60 (19), p.10516-10520 |
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| container_title | Angewandte Chemie International Edition |
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| creator | Hu, Xiangquan Han, Meirong Shao, Li Zhang, Chen Zhang, Le Kelley, Steven P. Zhang, Chi Lin, Jian Dalgarno, Scott J. Atwood, David A. Feng, Sisi Atwood, Jerry L. |
| description | We report the synthesis of a novel metal–organic capsule constructed from six pyrogallol[4]arene macrocycles, which are switched together by 16 FeIII and 16 CoII ions. This supramolecular structure is the first instance of a spheroidal heterometallic nanocage assembled through a one‐step metal–ligand coordination approach. This new assembly also demonstrates an important proof of concept through the formation of multiple heterometallic metal–metal interactions within the capsule framework. Photophysical and electrochemical studies of self‐assembled capsule films indicate their potential as semiconductors. These materials display unexpected photoelectric conversion properties, thus representing an emergent phenomenon in discrete metal–organic supramolecular assemblies.
A mixed Fe3+/Co2+‐seamed capsule comprising multiple heterometallic metal–metal interactions is presented. This capsule displays unexpected semiconducting and photoelectric conversion properties. |
| doi_str_mv | 10.1002/anie.202016077 |
| format | Article |
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A mixed Fe3+/Co2+‐seamed capsule comprising multiple heterometallic metal–metal interactions is presented. This capsule displays unexpected semiconducting and photoelectric conversion properties.</description><edition>International ed. in English</edition><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.202016077</identifier><identifier>PMID: 33403814</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>Assembly ; coordination cages ; Electrochemistry ; Electronics industry ; heterometallic metal–metal interactions ; Metals ; molecular magnetism ; molecule-based semiconductors ; photoelectric conversion ; Photoelectricity ; Pyrogallol</subject><ispartof>Angewandte Chemie International Edition, 2021-05, Vol.60 (19), p.10516-10520</ispartof><rights>2021 Wiley‐VCH GmbH</rights><rights>2021 Wiley-VCH GmbH.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4107-2ada86c34ac04163fd0aa44f640457dd18fe352faf2c5194202b51f25b93393e3</citedby><cites>FETCH-LOGICAL-c4107-2ada86c34ac04163fd0aa44f640457dd18fe352faf2c5194202b51f25b93393e3</cites><orcidid>0000-0002-3350-9618</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fanie.202016077$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fanie.202016077$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27903,27904,45553,45554</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/33403814$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Hu, Xiangquan</creatorcontrib><creatorcontrib>Han, Meirong</creatorcontrib><creatorcontrib>Shao, Li</creatorcontrib><creatorcontrib>Zhang, Chen</creatorcontrib><creatorcontrib>Zhang, Le</creatorcontrib><creatorcontrib>Kelley, Steven P.</creatorcontrib><creatorcontrib>Zhang, Chi</creatorcontrib><creatorcontrib>Lin, Jian</creatorcontrib><creatorcontrib>Dalgarno, Scott J.</creatorcontrib><creatorcontrib>Atwood, David A.</creatorcontrib><creatorcontrib>Feng, Sisi</creatorcontrib><creatorcontrib>Atwood, Jerry L.</creatorcontrib><title>Self‐Assembly of a Semiconductive and Photoactive Heterobimetallic Metal–Organic Capsule</title><title>Angewandte Chemie International Edition</title><addtitle>Angew Chem Int Ed Engl</addtitle><description>We report the synthesis of a novel metal–organic capsule constructed from six pyrogallol[4]arene macrocycles, which are switched together by 16 FeIII and 16 CoII ions. This supramolecular structure is the first instance of a spheroidal heterometallic nanocage assembled through a one‐step metal–ligand coordination approach. This new assembly also demonstrates an important proof of concept through the formation of multiple heterometallic metal–metal interactions within the capsule framework. Photophysical and electrochemical studies of self‐assembled capsule films indicate their potential as semiconductors. These materials display unexpected photoelectric conversion properties, thus representing an emergent phenomenon in discrete metal–organic supramolecular assemblies.
A mixed Fe3+/Co2+‐seamed capsule comprising multiple heterometallic metal–metal interactions is presented. This capsule displays unexpected semiconducting and photoelectric conversion properties.</description><subject>Assembly</subject><subject>coordination cages</subject><subject>Electrochemistry</subject><subject>Electronics industry</subject><subject>heterometallic metal–metal interactions</subject><subject>Metals</subject><subject>molecular magnetism</subject><subject>molecule-based semiconductors</subject><subject>photoelectric conversion</subject><subject>Photoelectricity</subject><subject>Pyrogallol</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNqFkE1Lw0AQhhdRrFavHiXgxUvqfibpsRS_oFpBvQnLZjOrKZtszSZKb_4EwX_YX-KW-gFePM0MPPMy8yB0QPCAYExPVF3CgGKKSYLTdAPtEEFJzNKUbYaeMxanmSA9tOv9LPBZhpNt1GOMY5YRvoMebsGa5dv7yHuocruInIlUdAtVqV1ddLotXyBSdRHdPLnWqfV8AS00Li8raJW1pY6uVs3y7WPaPIaDdDRWc99Z2ENbRlkP-1-1j-7PTu_GF_Fken45Hk1izQlOY6oKlSWacaUxJwkzBVaKc5NwzEVaFCQzwAQ1ylAtyJCHd3NBDBX5kLEhA9ZHx-vceeOeO_CtrEqvwVpVg-u8pDwVgoZ_SUCP_qAz1zV1uE5SQYKdjCYiUIM1pRvnfQNGzpuyUs1CEixX3uXKu_zxHhYOv2K7vILiB_8WHYDhGngtLSz-iZOj68vT3_BP-D-QKA</recordid><startdate>20210503</startdate><enddate>20210503</enddate><creator>Hu, Xiangquan</creator><creator>Han, Meirong</creator><creator>Shao, Li</creator><creator>Zhang, Chen</creator><creator>Zhang, Le</creator><creator>Kelley, Steven P.</creator><creator>Zhang, Chi</creator><creator>Lin, Jian</creator><creator>Dalgarno, Scott J.</creator><creator>Atwood, David A.</creator><creator>Feng, Sisi</creator><creator>Atwood, Jerry L.</creator><general>Wiley Subscription Services, Inc</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TM</scope><scope>K9.</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-3350-9618</orcidid></search><sort><creationdate>20210503</creationdate><title>Self‐Assembly of a Semiconductive and Photoactive Heterobimetallic Metal–Organic Capsule</title><author>Hu, Xiangquan ; Han, Meirong ; Shao, Li ; Zhang, Chen ; Zhang, Le ; Kelley, Steven P. ; Zhang, Chi ; Lin, Jian ; Dalgarno, Scott J. ; Atwood, David A. ; Feng, Sisi ; Atwood, Jerry L.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4107-2ada86c34ac04163fd0aa44f640457dd18fe352faf2c5194202b51f25b93393e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Assembly</topic><topic>coordination cages</topic><topic>Electrochemistry</topic><topic>Electronics industry</topic><topic>heterometallic metal–metal interactions</topic><topic>Metals</topic><topic>molecular magnetism</topic><topic>molecule-based semiconductors</topic><topic>photoelectric conversion</topic><topic>Photoelectricity</topic><topic>Pyrogallol</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hu, Xiangquan</creatorcontrib><creatorcontrib>Han, Meirong</creatorcontrib><creatorcontrib>Shao, Li</creatorcontrib><creatorcontrib>Zhang, Chen</creatorcontrib><creatorcontrib>Zhang, Le</creatorcontrib><creatorcontrib>Kelley, Steven P.</creatorcontrib><creatorcontrib>Zhang, Chi</creatorcontrib><creatorcontrib>Lin, Jian</creatorcontrib><creatorcontrib>Dalgarno, Scott J.</creatorcontrib><creatorcontrib>Atwood, David A.</creatorcontrib><creatorcontrib>Feng, Sisi</creatorcontrib><creatorcontrib>Atwood, Jerry L.</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hu, Xiangquan</au><au>Han, Meirong</au><au>Shao, Li</au><au>Zhang, Chen</au><au>Zhang, Le</au><au>Kelley, Steven P.</au><au>Zhang, Chi</au><au>Lin, Jian</au><au>Dalgarno, Scott J.</au><au>Atwood, David A.</au><au>Feng, Sisi</au><au>Atwood, Jerry L.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Self‐Assembly of a Semiconductive and Photoactive Heterobimetallic Metal–Organic Capsule</atitle><jtitle>Angewandte Chemie International Edition</jtitle><addtitle>Angew Chem Int Ed Engl</addtitle><date>2021-05-03</date><risdate>2021</risdate><volume>60</volume><issue>19</issue><spage>10516</spage><epage>10520</epage><pages>10516-10520</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><abstract>We report the synthesis of a novel metal–organic capsule constructed from six pyrogallol[4]arene macrocycles, which are switched together by 16 FeIII and 16 CoII ions. This supramolecular structure is the first instance of a spheroidal heterometallic nanocage assembled through a one‐step metal–ligand coordination approach. This new assembly also demonstrates an important proof of concept through the formation of multiple heterometallic metal–metal interactions within the capsule framework. Photophysical and electrochemical studies of self‐assembled capsule films indicate their potential as semiconductors. These materials display unexpected photoelectric conversion properties, thus representing an emergent phenomenon in discrete metal–organic supramolecular assemblies.
A mixed Fe3+/Co2+‐seamed capsule comprising multiple heterometallic metal–metal interactions is presented. This capsule displays unexpected semiconducting and photoelectric conversion properties.</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>33403814</pmid><doi>10.1002/anie.202016077</doi><tpages>5</tpages><edition>International ed. in English</edition><orcidid>https://orcid.org/0000-0002-3350-9618</orcidid></addata></record> |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Assembly coordination cages Electrochemistry Electronics industry heterometallic metal–metal interactions Metals molecular magnetism molecule-based semiconductors photoelectric conversion Photoelectricity Pyrogallol |
| title | Self‐Assembly of a Semiconductive and Photoactive Heterobimetallic Metal–Organic Capsule |
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