Reaction kinetics formulation with explicit radiation absorption effects of the photo-Fenton degradation of paracetamol under natural pH conditions
The degradation of paracetamol (PCT) in an aqueous medium using the Fenton and photo-Fenton reactions was investigated. The aim of this research was the development of a kinetic model based on a reaction mechanism, which includes two main intermediates of PCT degradation and the local volumetric rat...
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| description | The degradation of paracetamol (PCT) in an aqueous medium using the Fenton and photo-Fenton reactions was investigated. The aim of this research was the development of a kinetic model based on a reaction mechanism, which includes two main intermediates of PCT degradation and the local volumetric rate of photon absorption (LVRPA). Ferrioxalate was used as a catalyst and the working pH was adjusted to 5.5 (natural pH). Experimental work was planned through a D-optimal experimental design and performed in a flat plate reactor irradiated by a solar simulator. Hydrogen peroxide (HP) concentration, reaction temperature, and radiation level were the operating parameters. The photo-Fenton reaction allowed to reach a minimum relative PCT concentration of 2.01% compared to 5.04% achieved with Fenton reaction. Moreover, the photo-Fenton system required a 50% shorter reaction time and lower HP concentration than in dark conditions (90 min and 189 mg L
-1
vs. 180 min and 334 mg L
-1
, respectively). The experimental results were used to estimate the kinetic parameters of the proposed kinetic model employing a nonlinear, multi-parameter regression method. The values obtained from the normalized root-mean-square error (14.52, 1.96, 4.36, 13.16, and 8.72 % for PCT, benzoquinone, hydroquinone, HP, and oxalate, respectively) showed a good agreement between the predicted and experimental data. |
| doi_str_mv | 10.1007/s11356-020-11993-5 |
| format | Article |
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-1
vs. 180 min and 334 mg L
-1
, respectively). The experimental results were used to estimate the kinetic parameters of the proposed kinetic model employing a nonlinear, multi-parameter regression method. The values obtained from the normalized root-mean-square error (14.52, 1.96, 4.36, 13.16, and 8.72 % for PCT, benzoquinone, hydroquinone, HP, and oxalate, respectively) showed a good agreement between the predicted and experimental data.</description><identifier>ISSN: 0944-1344</identifier><identifier>EISSN: 1614-7499</identifier><identifier>DOI: 10.1007/s11356-020-11993-5</identifier><identifier>PMID: 33398729</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Absorption ; Advanced Oxidation/Reduction Technologies: An Perspective from Iberoamerican Countries ; Analgesics ; Aquatic Pollution ; Aqueous solutions ; Atmospheric Protection/Air Quality Control/Air Pollution ; Benzoquinone ; Catalysts ; Degradation ; Design of experiments ; Earth and Environmental Science ; Ecotoxicology ; Environment ; Environmental Chemistry ; Environmental Health ; Environmental science ; Environmental Sciences ; Environmental Sciences & Ecology ; Experimental design ; Flat plates ; Hydrogen peroxide ; Hydroquinone ; Intermediates ; Life Sciences & Biomedicine ; Mathematical models ; Oxalic acid ; Paracetamol ; Parameter estimation ; pH effects ; Photon absorption ; Radiation ; Radiation absorption ; Radiation measurement ; Reaction kinetics ; Reaction mechanisms ; Reaction time ; Science & Technology ; Solar simulators ; Waste Water Technology ; Water Management ; Water Pollution Control</subject><ispartof>Environmental science and pollution research international, 2021-05, Vol.28 (19), p.23946-23957</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH, DE part of Springer Nature 2021</rights><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH, DE part of Springer Nature 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>true</woscitedreferencessubscribed><woscitedreferencescount>8</woscitedreferencescount><woscitedreferencesoriginalsourcerecordid>wos000604878400043</woscitedreferencesoriginalsourcerecordid><citedby>FETCH-LOGICAL-c412t-276e674aecd5a1f3988369632573adcb1afb4925696e3ba7d2cf82ef5bfbe8953</citedby><cites>FETCH-LOGICAL-c412t-276e674aecd5a1f3988369632573adcb1afb4925696e3ba7d2cf82ef5bfbe8953</cites><orcidid>0000-0003-2435-878X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11356-020-11993-5$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11356-020-11993-5$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>315,781,785,27929,27930,39263,41493,42562,51324</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/33398729$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Giménez, Bárbara N.</creatorcontrib><creatorcontrib>Schenone, Agustina V.</creatorcontrib><creatorcontrib>Alfano, Orlando M.</creatorcontrib><creatorcontrib>Conte, Leandro O.</creatorcontrib><title>Reaction kinetics formulation with explicit radiation absorption effects of the photo-Fenton degradation of paracetamol under natural pH conditions</title><title>Environmental science and pollution research international</title><addtitle>Environ Sci Pollut Res</addtitle><addtitle>ENVIRON SCI POLLUT R</addtitle><addtitle>Environ Sci Pollut Res Int</addtitle><description>The degradation of paracetamol (PCT) in an aqueous medium using the Fenton and photo-Fenton reactions was investigated. The aim of this research was the development of a kinetic model based on a reaction mechanism, which includes two main intermediates of PCT degradation and the local volumetric rate of photon absorption (LVRPA). Ferrioxalate was used as a catalyst and the working pH was adjusted to 5.5 (natural pH). Experimental work was planned through a D-optimal experimental design and performed in a flat plate reactor irradiated by a solar simulator. Hydrogen peroxide (HP) concentration, reaction temperature, and radiation level were the operating parameters. The photo-Fenton reaction allowed to reach a minimum relative PCT concentration of 2.01% compared to 5.04% achieved with Fenton reaction. Moreover, the photo-Fenton system required a 50% shorter reaction time and lower HP concentration than in dark conditions (90 min and 189 mg L
-1
vs. 180 min and 334 mg L
-1
, respectively). The experimental results were used to estimate the kinetic parameters of the proposed kinetic model employing a nonlinear, multi-parameter regression method. The values obtained from the normalized root-mean-square error (14.52, 1.96, 4.36, 13.16, and 8.72 % for PCT, benzoquinone, hydroquinone, HP, and oxalate, respectively) showed a good agreement between the predicted and experimental data.</description><subject>Absorption</subject><subject>Advanced Oxidation/Reduction Technologies: An Perspective from Iberoamerican Countries</subject><subject>Analgesics</subject><subject>Aquatic Pollution</subject><subject>Aqueous solutions</subject><subject>Atmospheric Protection/Air Quality Control/Air Pollution</subject><subject>Benzoquinone</subject><subject>Catalysts</subject><subject>Degradation</subject><subject>Design of experiments</subject><subject>Earth and Environmental Science</subject><subject>Ecotoxicology</subject><subject>Environment</subject><subject>Environmental Chemistry</subject><subject>Environmental Health</subject><subject>Environmental science</subject><subject>Environmental Sciences</subject><subject>Environmental Sciences & 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Orlando M.</au><au>Conte, Leandro O.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Reaction kinetics formulation with explicit radiation absorption effects of the photo-Fenton degradation of paracetamol under natural pH conditions</atitle><jtitle>Environmental science and pollution research international</jtitle><stitle>Environ Sci Pollut Res</stitle><stitle>ENVIRON SCI POLLUT R</stitle><addtitle>Environ Sci Pollut Res Int</addtitle><date>2021-05-01</date><risdate>2021</risdate><volume>28</volume><issue>19</issue><spage>23946</spage><epage>23957</epage><pages>23946-23957</pages><issn>0944-1344</issn><eissn>1614-7499</eissn><abstract>The degradation of paracetamol (PCT) in an aqueous medium using the Fenton and photo-Fenton reactions was investigated. The aim of this research was the development of a kinetic model based on a reaction mechanism, which includes two main intermediates of PCT degradation and the local volumetric rate of photon absorption (LVRPA). Ferrioxalate was used as a catalyst and the working pH was adjusted to 5.5 (natural pH). Experimental work was planned through a D-optimal experimental design and performed in a flat plate reactor irradiated by a solar simulator. Hydrogen peroxide (HP) concentration, reaction temperature, and radiation level were the operating parameters. The photo-Fenton reaction allowed to reach a minimum relative PCT concentration of 2.01% compared to 5.04% achieved with Fenton reaction. Moreover, the photo-Fenton system required a 50% shorter reaction time and lower HP concentration than in dark conditions (90 min and 189 mg L
-1
vs. 180 min and 334 mg L
-1
, respectively). The experimental results were used to estimate the kinetic parameters of the proposed kinetic model employing a nonlinear, multi-parameter regression method. The values obtained from the normalized root-mean-square error (14.52, 1.96, 4.36, 13.16, and 8.72 % for PCT, benzoquinone, hydroquinone, HP, and oxalate, respectively) showed a good agreement between the predicted and experimental data.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><pmid>33398729</pmid><doi>10.1007/s11356-020-11993-5</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0003-2435-878X</orcidid></addata></record> |
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| ispartof | Environmental science and pollution research international, 2021-05, Vol.28 (19), p.23946-23957 |
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| source | Springer Online Journals Complete; Web of Science - Science Citation Index Expanded - 2021<img src="https://exlibris-pub.s3.amazonaws.com/fromwos-v2.jpg" /> |
| subjects | Absorption Advanced Oxidation/Reduction Technologies: An Perspective from Iberoamerican Countries Analgesics Aquatic Pollution Aqueous solutions Atmospheric Protection/Air Quality Control/Air Pollution Benzoquinone Catalysts Degradation Design of experiments Earth and Environmental Science Ecotoxicology Environment Environmental Chemistry Environmental Health Environmental science Environmental Sciences Environmental Sciences & Ecology Experimental design Flat plates Hydrogen peroxide Hydroquinone Intermediates Life Sciences & Biomedicine Mathematical models Oxalic acid Paracetamol Parameter estimation pH effects Photon absorption Radiation Radiation absorption Radiation measurement Reaction kinetics Reaction mechanisms Reaction time Science & Technology Solar simulators Waste Water Technology Water Management Water Pollution Control |
| title | Reaction kinetics formulation with explicit radiation absorption effects of the photo-Fenton degradation of paracetamol under natural pH conditions |
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