Regioselective B(3)-H bond activation based on an o-carboranyl dithiocarboxylate ligand and its derivatives

Herein, we describe the synthesis of tetraphenylphosphonium o-carboranyl dithiocarboxylate (Ligand 1) and methyldithiocarboxyl-o-carborane (Ligand 2). The complexes [Cp*M(o-C B H CS )Cl] (M = Ir (3); Rh (4)) and [Cp*M(o-C B H CS ) ] (M = Ir (5); Rh (6)) have been synthesized based on Ligand 1. The s...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2021-01, Vol.50 (3), p.1060-1068
Hauptverfasser:	Yuan, Run-Ze, Cui, Peng-Fei, Guo, Shu-Ting, Jin, Guo-Xin
Format:	Artikel
Sprache:	eng
Schlagworte:	Carborane Chemical analysis Coordination compounds Crystallography Crystals Derivatives Hydrogen bonds Infrared analysis Infrared spectroscopy Ligands NMR Nuclear magnetic resonance Single crystals Synthesis
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!