Mechanical rigidity of a shape-memory metal-organic framework increases by crystal downsizing

Soft porous nanocrystals with a pronounced shape-memory effect exhibit two- to three-fold increase in elastic modulus compared to the microcrystalline counterpart as determined by atomic force microscopy nanoindentation. The increase in rigidity is consistent with the known shape-memory effect displ...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2021-01, Vol.57 (1), p.89-92
Hauptverfasser:	Tiba, Al A, Conway, Matthew T, Hill, Collin S, Swenson, Dale C, MacGillivray, Leonard R, Tivanski, Alexei V
Format:	Artikel
Sprache:	eng
Schlagworte:	Atomic force microscopy Downsizing Heat treating Mechanical properties Metal-organic frameworks Microscopy Modulus of elasticity Nanocrystals Nanoindentation Rigidity Shape effects Shape memory X ray powder diffraction
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