Mechanical rigidity of a shape-memory metal-organic framework increases by crystal downsizing

Soft porous nanocrystals with a pronounced shape-memory effect exhibit two- to three-fold increase in elastic modulus compared to the microcrystalline counterpart as determined by atomic force microscopy nanoindentation. The increase in rigidity is consistent with the known shape-memory effect displayed by the framework solid at the nanoscale. Crystal downsizing can offer new avenues for tailoring the mechanical properties of metal-organic frameworks. The elastic modulus of a flexible metal-organic framework increases at the nanoscale as measured using AFM nanoindentation and accounts for a known shape-memory effect.