Biomass derived efficient conversion of levulinic acid for sustainable production of γ-valerolactone over cobalt based catalyst
[Display omitted] •Facile and efficient synthesis of cobalt loaded porous catalyst.•Noble-metal free, robust, and cost-effective heterogeneous catalytic system.•Lewis and Brønsted acidic sites together with active metallic cobalt ions promote activity.•Highly coke resistant and selective production...
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Veröffentlicht in: | Journal of hazardous materials 2021-03, Vol.405, p.123335-123335, Article 123335 |
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container_title | Journal of hazardous materials |
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creator | Barla, Madhu Krushna Velagala, Ram Rakesh Minpoor, Soumya Madduluri, Venkata Rao Srinivasu, Pavuluri |
description | [Display omitted]
•Facile and efficient synthesis of cobalt loaded porous catalyst.•Noble-metal free, robust, and cost-effective heterogeneous catalytic system.•Lewis and Brønsted acidic sites together with active metallic cobalt ions promote activity.•Highly coke resistant and selective production of γ-velarolactone.•Low temperature and scalable green catalytic process.
Biomass feedstocks offer very promising sustainable production of fuels and chemicals as fossil fuels generate greenhouse gases and are going to become scarce. Nevertheless, establishing value addition to biomass waste to produce commodity chemicals by combining economic and environmental performances is complex. In this context, hydrogenation of biomass based levulinic acid at normal atmospheric reaction conditions using robust cobalt supported on porous heterogeneous catalyst has been studied at 200 °C in a continuous process. The systematic investigation of Lewis acidic sites and low reaction temperature contribute to achieve 99 % conversion of levulinic acid and 80 % selectivity of γ-valerolactone. |
doi_str_mv | 10.1016/j.jhazmat.2020.123335 |
format | Article |
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•Facile and efficient synthesis of cobalt loaded porous catalyst.•Noble-metal free, robust, and cost-effective heterogeneous catalytic system.•Lewis and Brønsted acidic sites together with active metallic cobalt ions promote activity.•Highly coke resistant and selective production of γ-velarolactone.•Low temperature and scalable green catalytic process.
Biomass feedstocks offer very promising sustainable production of fuels and chemicals as fossil fuels generate greenhouse gases and are going to become scarce. Nevertheless, establishing value addition to biomass waste to produce commodity chemicals by combining economic and environmental performances is complex. In this context, hydrogenation of biomass based levulinic acid at normal atmospheric reaction conditions using robust cobalt supported on porous heterogeneous catalyst has been studied at 200 °C in a continuous process. The systematic investigation of Lewis acidic sites and low reaction temperature contribute to achieve 99 % conversion of levulinic acid and 80 % selectivity of γ-valerolactone.</description><identifier>ISSN: 0304-3894</identifier><identifier>EISSN: 1873-3336</identifier><identifier>DOI: 10.1016/j.jhazmat.2020.123335</identifier><identifier>PMID: 33317894</identifier><language>eng</language><publisher>Netherlands: Elsevier B.V</publisher><subject>Biomass ; Catalysis ; Cobalt ; Environmental friendly process ; Gamma-valerolactone ; Heterogeneous Co-based catalysis ; Lactones ; Levulinic acid ; Levulinic Acids</subject><ispartof>Journal of hazardous materials, 2021-03, Vol.405, p.123335-123335, Article 123335</ispartof><rights>2020 Elsevier B.V.</rights><rights>Copyright © 2020 Elsevier B.V. All rights reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c365t-afdad43f4b06f02055b7ffb67b9badc2e257c06ac0e41594df22641191574fe83</citedby><cites>FETCH-LOGICAL-c365t-afdad43f4b06f02055b7ffb67b9badc2e257c06ac0e41594df22641191574fe83</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jhazmat.2020.123335$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/33317894$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Barla, Madhu Krushna</creatorcontrib><creatorcontrib>Velagala, Ram Rakesh</creatorcontrib><creatorcontrib>Minpoor, Soumya</creatorcontrib><creatorcontrib>Madduluri, Venkata Rao</creatorcontrib><creatorcontrib>Srinivasu, Pavuluri</creatorcontrib><title>Biomass derived efficient conversion of levulinic acid for sustainable production of γ-valerolactone over cobalt based catalyst</title><title>Journal of hazardous materials</title><addtitle>J Hazard Mater</addtitle><description>[Display omitted]
•Facile and efficient synthesis of cobalt loaded porous catalyst.•Noble-metal free, robust, and cost-effective heterogeneous catalytic system.•Lewis and Brønsted acidic sites together with active metallic cobalt ions promote activity.•Highly coke resistant and selective production of γ-velarolactone.•Low temperature and scalable green catalytic process.
Biomass feedstocks offer very promising sustainable production of fuels and chemicals as fossil fuels generate greenhouse gases and are going to become scarce. Nevertheless, establishing value addition to biomass waste to produce commodity chemicals by combining economic and environmental performances is complex. In this context, hydrogenation of biomass based levulinic acid at normal atmospheric reaction conditions using robust cobalt supported on porous heterogeneous catalyst has been studied at 200 °C in a continuous process. The systematic investigation of Lewis acidic sites and low reaction temperature contribute to achieve 99 % conversion of levulinic acid and 80 % selectivity of γ-valerolactone.</description><subject>Biomass</subject><subject>Catalysis</subject><subject>Cobalt</subject><subject>Environmental friendly process</subject><subject>Gamma-valerolactone</subject><subject>Heterogeneous Co-based catalysis</subject><subject>Lactones</subject><subject>Levulinic acid</subject><subject>Levulinic Acids</subject><issn>0304-3894</issn><issn>1873-3336</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkM-OFCEQxolx4467PoKGo5ceoYFm5mR0479kk724Z1INRWRCNyvQnawn38n38JlkMqNXT1Upvvo-6kfIS862nPHhzWF7-AY_JqjbnvVt1gsh1BOy4TstutYPT8mGCSY7sdvLS_K8lANjjGsln5HL9s51m2_Iz_chTVAKdZjDio6i98EGnCu1aV4xl5BmmjyNuC4xzMFSsMFRnzItS6kQZhgj0oec3GLrWfz7V7dCxJwi2JpmpKk5NcMRYqUjlJZjoUJ8LPWaXHiIBV-c6xW5__jh683n7vbu05ebd7edFYOqHXgHTgovRzb4drBSo_Z-HPS4H8HZHnulLRvAMpRc7aXzfT9IzvdcaelxJ67I65Nv--n3BUs1UygWY4QZ01JMLzXrd2LQqknVSWpzKiWjNw85TJAfDWfmCN8czBm-OcI3J_ht79U5YhkndP-2_tJugrcnAbZD14DZlCNqiy5ktNW4FP4T8Qdmipwp</recordid><startdate>20210305</startdate><enddate>20210305</enddate><creator>Barla, Madhu Krushna</creator><creator>Velagala, Ram Rakesh</creator><creator>Minpoor, Soumya</creator><creator>Madduluri, Venkata Rao</creator><creator>Srinivasu, Pavuluri</creator><general>Elsevier B.V</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20210305</creationdate><title>Biomass derived efficient conversion of levulinic acid for sustainable production of γ-valerolactone over cobalt based catalyst</title><author>Barla, Madhu Krushna ; Velagala, Ram Rakesh ; Minpoor, Soumya ; Madduluri, Venkata Rao ; Srinivasu, Pavuluri</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c365t-afdad43f4b06f02055b7ffb67b9badc2e257c06ac0e41594df22641191574fe83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Biomass</topic><topic>Catalysis</topic><topic>Cobalt</topic><topic>Environmental friendly process</topic><topic>Gamma-valerolactone</topic><topic>Heterogeneous Co-based catalysis</topic><topic>Lactones</topic><topic>Levulinic acid</topic><topic>Levulinic Acids</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Barla, Madhu Krushna</creatorcontrib><creatorcontrib>Velagala, Ram Rakesh</creatorcontrib><creatorcontrib>Minpoor, Soumya</creatorcontrib><creatorcontrib>Madduluri, Venkata Rao</creatorcontrib><creatorcontrib>Srinivasu, Pavuluri</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of hazardous materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Barla, Madhu Krushna</au><au>Velagala, Ram Rakesh</au><au>Minpoor, Soumya</au><au>Madduluri, Venkata Rao</au><au>Srinivasu, Pavuluri</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Biomass derived efficient conversion of levulinic acid for sustainable production of γ-valerolactone over cobalt based catalyst</atitle><jtitle>Journal of hazardous materials</jtitle><addtitle>J Hazard Mater</addtitle><date>2021-03-05</date><risdate>2021</risdate><volume>405</volume><spage>123335</spage><epage>123335</epage><pages>123335-123335</pages><artnum>123335</artnum><issn>0304-3894</issn><eissn>1873-3336</eissn><abstract>[Display omitted]
•Facile and efficient synthesis of cobalt loaded porous catalyst.•Noble-metal free, robust, and cost-effective heterogeneous catalytic system.•Lewis and Brønsted acidic sites together with active metallic cobalt ions promote activity.•Highly coke resistant and selective production of γ-velarolactone.•Low temperature and scalable green catalytic process.
Biomass feedstocks offer very promising sustainable production of fuels and chemicals as fossil fuels generate greenhouse gases and are going to become scarce. Nevertheless, establishing value addition to biomass waste to produce commodity chemicals by combining economic and environmental performances is complex. In this context, hydrogenation of biomass based levulinic acid at normal atmospheric reaction conditions using robust cobalt supported on porous heterogeneous catalyst has been studied at 200 °C in a continuous process. The systematic investigation of Lewis acidic sites and low reaction temperature contribute to achieve 99 % conversion of levulinic acid and 80 % selectivity of γ-valerolactone.</abstract><cop>Netherlands</cop><pub>Elsevier B.V</pub><pmid>33317894</pmid><doi>10.1016/j.jhazmat.2020.123335</doi><tpages>1</tpages></addata></record> |
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subjects | Biomass Catalysis Cobalt Environmental friendly process Gamma-valerolactone Heterogeneous Co-based catalysis Lactones Levulinic acid Levulinic Acids |
title | Biomass derived efficient conversion of levulinic acid for sustainable production of γ-valerolactone over cobalt based catalyst |
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