Initial solvation of coal with tetralin under liquefaction conditions

Secondary vitroplast, produced by treating a Liddell vitrinite concentrate with tetralin in a continuous flow, packed-bed microreactor under a nitrogen pressure of 13.8 MPa at 360, 410 and 460 °C, has been analysed by i.r. spectroscopy, gel permeation chromatography, solid state 13C n.m.r. and refle...

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Veröffentlicht in:Fuel (Guildford) 1985-01, Vol.64 (4), p.454-456
Hauptverfasser: McPherson, Warren P., Foster, Neil R., Hastings, David W., Kalman, John R., Okada, Kiyofumi, Heng, Sammy
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container_end_page 456
container_issue 4
container_start_page 454
container_title Fuel (Guildford)
container_volume 64
creator McPherson, Warren P.
Foster, Neil R.
Hastings, David W.
Kalman, John R.
Okada, Kiyofumi
Heng, Sammy
description Secondary vitroplast, produced by treating a Liddell vitrinite concentrate with tetralin in a continuous flow, packed-bed microreactor under a nitrogen pressure of 13.8 MPa at 360, 410 and 460 °C, has been analysed by i.r. spectroscopy, gel permeation chromatography, solid state 13C n.m.r. and reflectance microscopy. Results showed that this intermediate in the liquefaction process had the same carbon aromaticity as the untreated vitrinite concentrate and that both its aromaticity and reflectance were independent of the temperature of formation. It was concluded that the initial solution of the vitrinite concentrate in tetralin involved no significant hydrogenation of the vitrinite.
doi_str_mv 10.1016/0016-2361(85)90076-6
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Results showed that this intermediate in the liquefaction process had the same carbon aromaticity as the untreated vitrinite concentrate and that both its aromaticity and reflectance were independent of the temperature of formation. It was concluded that the initial solution of the vitrinite concentrate in tetralin involved no significant hydrogenation of the vitrinite.</description><identifier>ISSN: 0016-2361</identifier><identifier>EISSN: 1873-7153</identifier><identifier>DOI: 10.1016/0016-2361(85)90076-6</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Applied sciences ; chemical structure ; coal ; Energy ; Exact sciences and technology ; Fuel processing. 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1873-7153
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source Elsevier ScienceDirect Journals
subjects Applied sciences
chemical structure
coal
Energy
Exact sciences and technology
Fuel processing. Carbochemistry and petrochemistry
Fuels
hydrogenation
liquefaction
short contact time
Solid fuel processing (coal, coke, brown coal, peat, wood, etc.)
vitroplast
title Initial solvation of coal with tetralin under liquefaction conditions
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