Ranking Ligands by Their Ability to Ease (C6F5)2NiIIL → Ni0L + (C6F5)2 Coupling versus Hydrolysis: Outstanding Activity of PEWO Ligands

The NiII literature complex cis-[Ni­(C6F5)2(THF)2] is a synthon of cis-Ni­(C6F5)2 that allows us to establish a protocol to measure and compare the ligand effect on the NiII → Ni0 reductive elimination step (coupling), often critical in catalytic processes. Several ligands of different types were su...

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Veröffentlicht in:	Inorganic chemistry 2020-12, Vol.59 (24), p.18287-18294
Hauptverfasser:	Ponce-de-León, Jaime, Gioria, Estefania, Martínez-Ilarduya, Jesús M, Espinet, Pablo
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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