Reconstructive phase transitions and effective adsorbate-adsorbate interactions: H/Mo(100) and H/W(100)
Low-energy electron-diffraction and infrared-absorption measurements of H/Mo(100) and H/W(100) surfaces show that, at low hydrogen coverages, the effective H--H interactions are very different for the two substrates, leading to island formation on Mo(100) and to a uniform H layer on W(100). The resu...
Gespeichert in:
| Veröffentlicht in: | Physical review letters 1987-05, Vol.58 (18), p.1877-1880 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1880 |
|---|---|
| container_issue | 18 |
| container_start_page | 1877 |
| container_title | Physical review letters |
| container_volume | 58 |
| creator | PRYBYLA, J. A ESTRUP, P. J YING, S. C CHABAL, Y. J CHRISTMAN, S. B |
| description | Low-energy electron-diffraction and infrared-absorption measurements of H/Mo(100) and H/W(100) surfaces show that, at low hydrogen coverages, the effective H--H interactions are very different for the two substrates, leading to island formation on Mo(100) and to a uniform H layer on W(100). The results can be explained by a phonon-mediated interaction mechanism for the H adatoms, according to which the difference in behavior is due to the difference in the coupling between substrate distortions induced by the individual adatoms. It is concluded that a realistic treatment of the adatom interactions should go beyond the rigid-substrate model and include the crucial role of soft phonons. 21 ref.--AA |
| doi_str_mv | 10.1103/physrevlett.58.1877 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_24658341</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1859232218</sourcerecordid><originalsourceid>FETCH-LOGICAL-c429t-93f5aff676826a302470f8d99833e72c4403878fca0db2532ea2268fbce7ef663</originalsourceid><addsrcrecordid>eNp9kV1LwzAYhYMobk5_gSC9EJkX3fLVJvVOhjphogzFy5Klb1yla2eSDvbvzT4YXnmVhPOcvLznIHRJ8IAQzIbL-dpZWFXg_SCRAyKFOEJdgkUWC0L4MepizEicYSw66My5b4wxoak8RR0SFJ6kpIu-pqCb2nnbal-uIFrOlYPIW1W70pdBiVRdRGAM7HRVuMbOlIf4cIvK2oNVeovfRePhS9MPA263zvHwc_s4RydGVQ4u9mcPfTw-vI_G8eT16Xl0P4k1p5mPM2YSZUwqUklTxTDlAhtZZJlkDATVnGMmhTRa4WJGE0ZB0bCSmWkQYNKU9dDN7t-lbX5acD5flE5DVakamtbllKeJZJwEsP8vSGSSUUYpkQFlO1TbxoXITb605ULZdU5wvqkifwtVTGE1CVXkicw3VQTX1X5AO1tA8cezyz4A13tAOa0qEzLXpTtwkjJOWcZ-AVU9k1Y</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1859232218</pqid></control><display><type>article</type><title>Reconstructive phase transitions and effective adsorbate-adsorbate interactions: H/Mo(100) and H/W(100)</title><source>American Physical Society Journals</source><creator>PRYBYLA, J. A ; ESTRUP, P. J ; YING, S. C ; CHABAL, Y. J ; CHRISTMAN, S. B</creator><creatorcontrib>PRYBYLA, J. A ; ESTRUP, P. J ; YING, S. C ; CHABAL, Y. J ; CHRISTMAN, S. B</creatorcontrib><description>Low-energy electron-diffraction and infrared-absorption measurements of H/Mo(100) and H/W(100) surfaces show that, at low hydrogen coverages, the effective H--H interactions are very different for the two substrates, leading to island formation on Mo(100) and to a uniform H layer on W(100). The results can be explained by a phonon-mediated interaction mechanism for the H adatoms, according to which the difference in behavior is due to the difference in the coupling between substrate distortions induced by the individual adatoms. It is concluded that a realistic treatment of the adatom interactions should go beyond the rigid-substrate model and include the crucial role of soft phonons. 21 ref.--AA</description><identifier>ISSN: 0031-9007</identifier><identifier>EISSN: 1079-7114</identifier><identifier>DOI: 10.1103/physrevlett.58.1877</identifier><identifier>PMID: 10034561</identifier><identifier>CODEN: PRLTAO</identifier><language>eng</language><publisher>Ridge, NY: American Physical Society</publisher><subject>Applied sciences ; Chemistry ; Cross-disciplinary physics: materials science; rheology ; Exact sciences and technology ; General and physical chemistry ; Materials science ; Metals, semimetals and alloys ; Metals. Metallurgy ; Physics ; Solid-gas interface ; Specific materials ; Surface physical chemistry</subject><ispartof>Physical review letters, 1987-05, Vol.58 (18), p.1877-1880</ispartof><rights>1987 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c429t-93f5aff676826a302470f8d99833e72c4403878fca0db2532ea2268fbce7ef663</citedby><cites>FETCH-LOGICAL-c429t-93f5aff676826a302470f8d99833e72c4403878fca0db2532ea2268fbce7ef663</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,781,785,2877,2878,27929,27930</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=8234239$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/10034561$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>PRYBYLA, J. A</creatorcontrib><creatorcontrib>ESTRUP, P. J</creatorcontrib><creatorcontrib>YING, S. C</creatorcontrib><creatorcontrib>CHABAL, Y. J</creatorcontrib><creatorcontrib>CHRISTMAN, S. B</creatorcontrib><title>Reconstructive phase transitions and effective adsorbate-adsorbate interactions: H/Mo(100) and H/W(100)</title><title>Physical review letters</title><addtitle>Phys Rev Lett</addtitle><description>Low-energy electron-diffraction and infrared-absorption measurements of H/Mo(100) and H/W(100) surfaces show that, at low hydrogen coverages, the effective H--H interactions are very different for the two substrates, leading to island formation on Mo(100) and to a uniform H layer on W(100). The results can be explained by a phonon-mediated interaction mechanism for the H adatoms, according to which the difference in behavior is due to the difference in the coupling between substrate distortions induced by the individual adatoms. It is concluded that a realistic treatment of the adatom interactions should go beyond the rigid-substrate model and include the crucial role of soft phonons. 21 ref.--AA</description><subject>Applied sciences</subject><subject>Chemistry</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Materials science</subject><subject>Metals, semimetals and alloys</subject><subject>Metals. Metallurgy</subject><subject>Physics</subject><subject>Solid-gas interface</subject><subject>Specific materials</subject><subject>Surface physical chemistry</subject><issn>0031-9007</issn><issn>1079-7114</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1987</creationdate><recordtype>article</recordtype><recordid>eNp9kV1LwzAYhYMobk5_gSC9EJkX3fLVJvVOhjphogzFy5Klb1yla2eSDvbvzT4YXnmVhPOcvLznIHRJ8IAQzIbL-dpZWFXg_SCRAyKFOEJdgkUWC0L4MepizEicYSw66My5b4wxoak8RR0SFJ6kpIu-pqCb2nnbal-uIFrOlYPIW1W70pdBiVRdRGAM7HRVuMbOlIf4cIvK2oNVeovfRePhS9MPA263zvHwc_s4RydGVQ4u9mcPfTw-vI_G8eT16Xl0P4k1p5mPM2YSZUwqUklTxTDlAhtZZJlkDATVnGMmhTRa4WJGE0ZB0bCSmWkQYNKU9dDN7t-lbX5acD5flE5DVakamtbllKeJZJwEsP8vSGSSUUYpkQFlO1TbxoXITb605ULZdU5wvqkifwtVTGE1CVXkicw3VQTX1X5AO1tA8cezyz4A13tAOa0qEzLXpTtwkjJOWcZ-AVU9k1Y</recordid><startdate>19870504</startdate><enddate>19870504</enddate><creator>PRYBYLA, J. A</creator><creator>ESTRUP, P. J</creator><creator>YING, S. C</creator><creator>CHABAL, Y. J</creator><creator>CHRISTMAN, S. B</creator><general>American Physical Society</general><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>19870504</creationdate><title>Reconstructive phase transitions and effective adsorbate-adsorbate interactions: H/Mo(100) and H/W(100)</title><author>PRYBYLA, J. A ; ESTRUP, P. J ; YING, S. C ; CHABAL, Y. J ; CHRISTMAN, S. B</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c429t-93f5aff676826a302470f8d99833e72c4403878fca0db2532ea2268fbce7ef663</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1987</creationdate><topic>Applied sciences</topic><topic>Chemistry</topic><topic>Cross-disciplinary physics: materials science; rheology</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Materials science</topic><topic>Metals, semimetals and alloys</topic><topic>Metals. Metallurgy</topic><topic>Physics</topic><topic>Solid-gas interface</topic><topic>Specific materials</topic><topic>Surface physical chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>PRYBYLA, J. A</creatorcontrib><creatorcontrib>ESTRUP, P. J</creatorcontrib><creatorcontrib>YING, S. C</creatorcontrib><creatorcontrib>CHABAL, Y. J</creatorcontrib><creatorcontrib>CHRISTMAN, S. B</creatorcontrib><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Physical review letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>PRYBYLA, J. A</au><au>ESTRUP, P. J</au><au>YING, S. C</au><au>CHABAL, Y. J</au><au>CHRISTMAN, S. B</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Reconstructive phase transitions and effective adsorbate-adsorbate interactions: H/Mo(100) and H/W(100)</atitle><jtitle>Physical review letters</jtitle><addtitle>Phys Rev Lett</addtitle><date>1987-05-04</date><risdate>1987</risdate><volume>58</volume><issue>18</issue><spage>1877</spage><epage>1880</epage><pages>1877-1880</pages><issn>0031-9007</issn><eissn>1079-7114</eissn><coden>PRLTAO</coden><abstract>Low-energy electron-diffraction and infrared-absorption measurements of H/Mo(100) and H/W(100) surfaces show that, at low hydrogen coverages, the effective H--H interactions are very different for the two substrates, leading to island formation on Mo(100) and to a uniform H layer on W(100). The results can be explained by a phonon-mediated interaction mechanism for the H adatoms, according to which the difference in behavior is due to the difference in the coupling between substrate distortions induced by the individual adatoms. It is concluded that a realistic treatment of the adatom interactions should go beyond the rigid-substrate model and include the crucial role of soft phonons. 21 ref.--AA</abstract><cop>Ridge, NY</cop><pub>American Physical Society</pub><pmid>10034561</pmid><doi>10.1103/physrevlett.58.1877</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0031-9007 |
| ispartof | Physical review letters, 1987-05, Vol.58 (18), p.1877-1880 |
| issn | 0031-9007 1079-7114 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_24658341 |
| source | American Physical Society Journals |
| subjects | Applied sciences Chemistry Cross-disciplinary physics: materials science rheology Exact sciences and technology General and physical chemistry Materials science Metals, semimetals and alloys Metals. Metallurgy Physics Solid-gas interface Specific materials Surface physical chemistry |
| title | Reconstructive phase transitions and effective adsorbate-adsorbate interactions: H/Mo(100) and H/W(100) |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-15T06%3A56%3A47IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Reconstructive%20phase%20transitions%20and%20effective%20adsorbate-adsorbate%20interactions:%20H/Mo(100)%20and%20H/W(100)&rft.jtitle=Physical%20review%20letters&rft.au=PRYBYLA,%20J.%20A&rft.date=1987-05-04&rft.volume=58&rft.issue=18&rft.spage=1877&rft.epage=1880&rft.pages=1877-1880&rft.issn=0031-9007&rft.eissn=1079-7114&rft.coden=PRLTAO&rft_id=info:doi/10.1103/physrevlett.58.1877&rft_dat=%3Cproquest_cross%3E1859232218%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1859232218&rft_id=info:pmid/10034561&rfr_iscdi=true |