Palladium‐Catalyzed Site‐Selective [3+2] Annulation via Benzylic and meta C−H Bond Activation

The palladium‐catalyzed [3+2] annulation of aromatic amides with maleimides via the activation of ortho benzylic C−H and meta C−H bonds is reported. Carboxamide and anilide type substrates that contain a 2‐methylthiophenyl group both participate in this [3+2] annulation, indicating that the presence...

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Veröffentlicht in:	Angewandte Chemie International Edition 2021-03, Vol.60 (10), p.5189-5192
Hauptverfasser:	He, Qiyuan, Chatani, Naoto
Format:	Artikel
Sprache:	eng
Schlagworte:	[3+2] annulation Amides Chemical reactions C–H activation Hydrogen bonds Organic chemistry Palladium site selectivity Substrates
Online-Zugang:	Volltext
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