Lithium cycling performance in improved lithium hexafluoroarsenate/2-methyl tetrahydrofuran electrolytes
Lithium hexafluorarsenate/2-methyl tetrahydrofuran electrolytes have been prepared, purified, and evaluated using half-cell galvanostatic lithium cycling, cyclic voltammetry, plus colorimetric, gas chromatographic, and UV absorption techniques. Superior electrolytes have been prepared yielding repro...
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| Veröffentlicht in: | J. Electrochem. Soc.; (United States) 1985-03, Vol.132 (3), p.529-533 |
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| container_title | J. Electrochem. Soc.; (United States) |
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| creator | DESJARDINS, C. D CADGER, T. G SALTER, R. S DONALDSON, G CASEY, E. J |
| description | Lithium hexafluorarsenate/2-methyl tetrahydrofuran electrolytes have been prepared, purified, and evaluated using half-cell galvanostatic lithium cycling, cyclic voltammetry, plus colorimetric, gas chromatographic, and UV absorption techniques. Superior electrolytes have been prepared yielding reproducible cycling efficiencies in excess of 97 percent. Static aging trails at ambient temperature clearly demonstrate deterioration in cycling performance with time. This decline in performance is related to electrolyte degradation, possibly arising from the formation of peroxides. However, studies of various battery testing regimes on 1M LiAsF6/2Me-THF electrolyte support the system's battery potential with respect to both rate capability and shelf-life characteristics. |
| doi_str_mv | 10.1149/1.2113881 |
| format | Article |
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D ; CADGER, T. G ; SALTER, R. S ; DONALDSON, G ; CASEY, E. J</creator><creatorcontrib>DESJARDINS, C. D ; CADGER, T. G ; SALTER, R. S ; DONALDSON, G ; CASEY, E. J ; Research and Productivity Council, Fredericton, New Brunswick</creatorcontrib><description>Lithium hexafluorarsenate/2-methyl tetrahydrofuran electrolytes have been prepared, purified, and evaluated using half-cell galvanostatic lithium cycling, cyclic voltammetry, plus colorimetric, gas chromatographic, and UV absorption techniques. Superior electrolytes have been prepared yielding reproducible cycling efficiencies in excess of 97 percent. Static aging trails at ambient temperature clearly demonstrate deterioration in cycling performance with time. This decline in performance is related to electrolyte degradation, possibly arising from the formation of peroxides. However, studies of various battery testing regimes on 1M LiAsF6/2Me-THF electrolyte support the system's battery potential with respect to both rate capability and shelf-life characteristics.</description><identifier>ISSN: 0013-4651</identifier><identifier>EISSN: 1945-7111</identifier><identifier>DOI: 10.1149/1.2113881</identifier><identifier>CODEN: JESOAN</identifier><language>eng</language><publisher>Pennington, NJ: Electrochemical Society</publisher><subject>250902 - Energy Storage- Batteries- Performance & Testing ; 250903 - Energy Storage- Batteries- Materials, Components, & Auxiliaries ; 400400 - Electrochemistry ; Adsorption ; ALKALI METALS ; ARSENATES ; ARSENIC COMPOUNDS ; CHEMICAL COMPOSITION ; CHEMICAL PREPARATION ; CHEMISTRY ; ELECTRIC BATTERIES ; ELECTROCHEMICAL CELLS ; ELECTROCHEMISTRY ; Electrodeposition ; ELECTROLYTES ; ELEMENTS ; ENERGY STORAGE ; Exact sciences and technology ; FLUORINE COMPOUNDS ; FURANS ; General and physical chemistry ; HALOGEN COMPOUNDS ; HETEROCYCLIC COMPOUNDS ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; LITHIUM ; MATERIALS TESTING ; METAL-NONMETAL BATTERIES ; METALS ; MTHF ; ORGANIC COMPOUNDS ; ORGANIC OXYGEN COMPOUNDS ; OXYGEN COMPOUNDS ; PERFORMANCE TESTING ; PEROXIDES ; PURIFICATION ; SERVICE LIFE ; Study of interfaces ; SYNTHESIS ; TESTING ; TETRAHYDROFURAN ; Transport phenomena ; VOLTAMETRY</subject><ispartof>J. 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S</creatorcontrib><creatorcontrib>DONALDSON, G</creatorcontrib><creatorcontrib>CASEY, E. J</creatorcontrib><creatorcontrib>Research and Productivity Council, Fredericton, New Brunswick</creatorcontrib><title>Lithium cycling performance in improved lithium hexafluoroarsenate/2-methyl tetrahydrofuran electrolytes</title><title>J. Electrochem. Soc.; (United States)</title><description>Lithium hexafluorarsenate/2-methyl tetrahydrofuran electrolytes have been prepared, purified, and evaluated using half-cell galvanostatic lithium cycling, cyclic voltammetry, plus colorimetric, gas chromatographic, and UV absorption techniques. Superior electrolytes have been prepared yielding reproducible cycling efficiencies in excess of 97 percent. Static aging trails at ambient temperature clearly demonstrate deterioration in cycling performance with time. This decline in performance is related to electrolyte degradation, possibly arising from the formation of peroxides. However, studies of various battery testing regimes on 1M LiAsF6/2Me-THF electrolyte support the system's battery potential with respect to both rate capability and shelf-life characteristics.</description><subject>250902 - Energy Storage- Batteries- Performance & Testing</subject><subject>250903 - Energy Storage- Batteries- Materials, Components, & Auxiliaries</subject><subject>400400 - Electrochemistry</subject><subject>Adsorption</subject><subject>ALKALI METALS</subject><subject>ARSENATES</subject><subject>ARSENIC COMPOUNDS</subject><subject>CHEMICAL COMPOSITION</subject><subject>CHEMICAL PREPARATION</subject><subject>CHEMISTRY</subject><subject>ELECTRIC BATTERIES</subject><subject>ELECTROCHEMICAL CELLS</subject><subject>ELECTROCHEMISTRY</subject><subject>Electrodeposition</subject><subject>ELECTROLYTES</subject><subject>ELEMENTS</subject><subject>ENERGY STORAGE</subject><subject>Exact sciences and technology</subject><subject>FLUORINE COMPOUNDS</subject><subject>FURANS</subject><subject>General and physical chemistry</subject><subject>HALOGEN COMPOUNDS</subject><subject>HETEROCYCLIC COMPOUNDS</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>LITHIUM</subject><subject>MATERIALS TESTING</subject><subject>METAL-NONMETAL BATTERIES</subject><subject>METALS</subject><subject>MTHF</subject><subject>ORGANIC COMPOUNDS</subject><subject>ORGANIC OXYGEN COMPOUNDS</subject><subject>OXYGEN COMPOUNDS</subject><subject>PERFORMANCE TESTING</subject><subject>PEROXIDES</subject><subject>PURIFICATION</subject><subject>SERVICE LIFE</subject><subject>Study of interfaces</subject><subject>SYNTHESIS</subject><subject>TESTING</subject><subject>TETRAHYDROFURAN</subject><subject>Transport phenomena</subject><subject>VOLTAMETRY</subject><issn>0013-4651</issn><issn>1945-7111</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1985</creationdate><recordtype>article</recordtype><recordid>eNo90E1LxDAQBuAgCq6rB_9BERE8dDeTZNvNUcQvWPCi55BNJzaSNmuSiv33VnbxNAw8M8y8hFwCXQAIuYQFA-DrNRyRGUixKmsAOCYzSoGXolrBKTlL6XNqYS3qGWk3Lrdu6AozGu_6j2KH0YbY6d5g4frCdbsYvrEp_MG1-KOtH0IMOibsdcYlKzvM7eiLjDnqdmxisEPUfYEeTY7BjxnTOTmx2ie8ONQ5eX98eLt_LjevTy_3d5vScBC5RKqNbahuKrPVjDZbBBSUN2tZ27pmIIDZSmigwAy1lLOGMs2lNAIaYNLyObna7w0pO5WMy2haE_p-OkVVQq5YvZrQzR5Nz30NmLLqXDLove4xDEkxUcEE5QRv99DEkFJEq3bRdTqOCqj6C1yBOgQ-2evDUp2M9nZKwLj0PyCh4oJR_guNjIFF</recordid><startdate>19850301</startdate><enddate>19850301</enddate><creator>DESJARDINS, C. 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D</creatorcontrib><creatorcontrib>CADGER, T. G</creatorcontrib><creatorcontrib>SALTER, R. S</creatorcontrib><creatorcontrib>DONALDSON, G</creatorcontrib><creatorcontrib>CASEY, E. J</creatorcontrib><creatorcontrib>Research and Productivity Council, Fredericton, New Brunswick</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>OSTI.GOV</collection><jtitle>J. Electrochem. Soc.; (United States)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>DESJARDINS, C. D</au><au>CADGER, T. G</au><au>SALTER, R. S</au><au>DONALDSON, G</au><au>CASEY, E. J</au><aucorp>Research and Productivity Council, Fredericton, New Brunswick</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Lithium cycling performance in improved lithium hexafluoroarsenate/2-methyl tetrahydrofuran electrolytes</atitle><jtitle>J. Electrochem. Soc.; (United States)</jtitle><date>1985-03-01</date><risdate>1985</risdate><volume>132</volume><issue>3</issue><spage>529</spage><epage>533</epage><pages>529-533</pages><issn>0013-4651</issn><eissn>1945-7111</eissn><coden>JESOAN</coden><abstract>Lithium hexafluorarsenate/2-methyl tetrahydrofuran electrolytes have been prepared, purified, and evaluated using half-cell galvanostatic lithium cycling, cyclic voltammetry, plus colorimetric, gas chromatographic, and UV absorption techniques. Superior electrolytes have been prepared yielding reproducible cycling efficiencies in excess of 97 percent. Static aging trails at ambient temperature clearly demonstrate deterioration in cycling performance with time. This decline in performance is related to electrolyte degradation, possibly arising from the formation of peroxides. However, studies of various battery testing regimes on 1M LiAsF6/2Me-THF electrolyte support the system's battery potential with respect to both rate capability and shelf-life characteristics.</abstract><cop>Pennington, NJ</cop><pub>Electrochemical Society</pub><doi>10.1149/1.2113881</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0013-4651 |
| ispartof | J. Electrochem. Soc.; (United States), 1985-03, Vol.132 (3), p.529-533 |
| issn | 0013-4651 1945-7111 |
| language | eng |
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| subjects | 250902 - Energy Storage- Batteries- Performance & Testing 250903 - Energy Storage- Batteries- Materials, Components, & Auxiliaries 400400 - Electrochemistry Adsorption ALKALI METALS ARSENATES ARSENIC COMPOUNDS CHEMICAL COMPOSITION CHEMICAL PREPARATION CHEMISTRY ELECTRIC BATTERIES ELECTROCHEMICAL CELLS ELECTROCHEMISTRY Electrodeposition ELECTROLYTES ELEMENTS ENERGY STORAGE Exact sciences and technology FLUORINE COMPOUNDS FURANS General and physical chemistry HALOGEN COMPOUNDS HETEROCYCLIC COMPOUNDS INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY LITHIUM MATERIALS TESTING METAL-NONMETAL BATTERIES METALS MTHF ORGANIC COMPOUNDS ORGANIC OXYGEN COMPOUNDS OXYGEN COMPOUNDS PERFORMANCE TESTING PEROXIDES PURIFICATION SERVICE LIFE Study of interfaces SYNTHESIS TESTING TETRAHYDROFURAN Transport phenomena VOLTAMETRY |
| title | Lithium cycling performance in improved lithium hexafluoroarsenate/2-methyl tetrahydrofuran electrolytes |
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