Detailed course of the O + HO2 reaction

Detailed course of the O + HO2 reaction

The elementary radical-radical reactions that are of such importance in laser, astrophysical, atmospheric, and combustion processes are increasingly open to direct rate measurement. Attention is presently given to the O + HO2 reaction, which has only one exothermic product channel: OH + O2. Isotopic...

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Veröffentlicht in:The Journal of chemical physics 1985-01, Vol.82 (1), p.592-593
Hauptverfasser: Sridharan, U. C., Klein, F. S., Kaufman, F.
Format: Artikel
Sprache:eng
Schlagworte:
Applied sciences
Chemistry
Exact sciences and technology
Inorganic And Physical Chemistry
Inorganic chemistry and origins of life
Kinetics and mechanism of reactions
Other techniques and industries
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container_title The Journal of chemical physics
container_volume 82
creator Sridharan, U. C.
Klein, F. S.
Kaufman, F.
description The elementary radical-radical reactions that are of such importance in laser, astrophysical, atmospheric, and combustion processes are increasingly open to direct rate measurement. Attention is presently given to the O + HO2 reaction, which has only one exothermic product channel: OH + O2. Isotopic product analysis was conducted spectroscopically using laser-induced fluorescence of OH. It is found that the simple atom-radical reaction takes place by way of the rapid formation and breakup of an unexpected radical intermediate, thereby raising questions as to the formation, thermochemistry, and decomposition of poorly known products in many other radical-radical reaction systems.
doi_str_mv 10.1063/1.448973
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source AIP Digital Archive; NASA Technical Reports Server
subjects Applied sciences
Chemistry
Exact sciences and technology
Inorganic And Physical Chemistry
Inorganic chemistry and origins of life
Kinetics and mechanism of reactions
Other techniques and industries
title Detailed course of the O + HO2 reaction
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