Incorporation of V2O5 nanorods into perovskite photodetectors as an alternative approach to enhance device performance: a step towards stability against ambient water species

Numerous reports have been made in the literature on the usability of a halide perovskite, namely methyl ammonium lead iodide (CH3NH3PbI3), as a light harvesting material. Suitable optimization in material composition and synthesis has led to an improvement in device performance. However, the suscep...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2020-11, Vol.49 (44), p.15788-15799
Hauptverfasser: Besra, Nripen, Sardar, Kausik, Maiti, Soumen, Sarkar, Pranab Kumar, Tufan, Paul, Thakur, Subhasish, Majumdar, Gautam, Chattopadhyay, Kalyan Kumar
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container_end_page 15799
container_issue 44
container_start_page 15788
container_title Dalton transactions : an international journal of inorganic chemistry
container_volume 49
creator Besra, Nripen
Sardar, Kausik
Maiti, Soumen
Sarkar, Pranab Kumar
Tufan, Paul
Thakur, Subhasish
Majumdar, Gautam
Chattopadhyay, Kalyan Kumar
description Numerous reports have been made in the literature on the usability of a halide perovskite, namely methyl ammonium lead iodide (CH3NH3PbI3), as a light harvesting material. Suitable optimization in material composition and synthesis has led to an improvement in device performance. However, the susceptibility of CH3NH3PbI3 towards atmospheric water is an alarming issue which hinders its long-term application in day-to-day life. Herein, low temperature synthesized V2O5 nanorods are incorporated into the CH3NH3PbI3 matrix to facilitate carrier dynamics by interface engineering. The optimized hybrid sample exhibits a much improved and stable photo-response behaviour than the pristine building blocks. Additionally, the modified perovskite shows improved hydrophobicity in the form of small-scale surface undulations due to the incorporation of V2O5 nanorods into it. This way, we have solved two problems with one single action, firstly by improving the device performance and secondly by stabilizing the sample against ambient water species.
doi_str_mv 10.1039/d0dt03177a
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Hydrophobicity
Low temperature
Nanorods
Optimization
Perovskites
Vanadium pentoxide
title Incorporation of V2O5 nanorods into perovskite photodetectors as an alternative approach to enhance device performance: a step towards stability against ambient water species
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