Electrochemical Applications of Ferrocene‐Based Coordination Polymers

Ferrocene and its derivatives, especially ferrocene‐based coordination polymers (Fc‐CPs), offer the benefits of high thermal stability, two stable redox states, fast electron transfer, and excellent charge/discharge efficiency, thus holding great promise for electrochemical applications. Herein, we...

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Veröffentlicht in:ChemPlusChem (Weinheim, Germany) Germany), 2020-11, Vol.85 (11), p.2397-2418
Hauptverfasser: Hu, Mao‐Lin, Abbasi‐Azad, Mahsa, Habibi, Behnam, Rouhani, Farzaneh, Moghanni‐Bavil‐Olyaei, Hamed, Liu, Kuan‐Guan, Morsali, Ali
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container_issue 11
container_start_page 2397
container_title ChemPlusChem (Weinheim, Germany)
container_volume 85
creator Hu, Mao‐Lin
Abbasi‐Azad, Mahsa
Habibi, Behnam
Rouhani, Farzaneh
Moghanni‐Bavil‐Olyaei, Hamed
Liu, Kuan‐Guan
Morsali, Ali
description Ferrocene and its derivatives, especially ferrocene‐based coordination polymers (Fc‐CPs), offer the benefits of high thermal stability, two stable redox states, fast electron transfer, and excellent charge/discharge efficiency, thus holding great promise for electrochemical applications. Herein, we describe the synthesis and electrochemical applications of Fc‐CPs and reveal how the incorporation of ferrocene units into coordination polymers containing other metals results in unprecedented properties. Moreover, we discuss the usage of Fc‐CPs in supercapacitors, batteries, and sensors as well as further applications of these polymers, for example in electrocatalysts, water purification systems, adsorption/storage systems. Iron strength: The incorporation of ferrocene as an organometallic building block into coordination polymers containing other metals to impart certain properties can afford attractive structures denoted as ferrocene‐based coordination polymers. This Review focuses on the synthesis and electrochemical applications (e. g., supercapacitors, batteries, electrosensors, and electrocatalysts) of these coordination polymers.
doi_str_mv 10.1002/cplu.202000584
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subjects batteries
Charge efficiency
Charge transfer
Chemistry
Coordination polymers
Electrocatalysts
Electrochemistry
Electron transfer
ferrocene
Polymers
Storage systems
supercapacitors
Thermal stability
Water purification
title Electrochemical Applications of Ferrocene‐Based Coordination Polymers
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