Phosphine Carboxylate—Probing the Edge of Stability of a Carbon Dioxide Adduct with Dihydrogenphosphide

We present a new adduct of carbon dioxide with dihydrogenphosphide, that may be prepared either by direct reaction of NaPH2 with carbon dioxide or by hydrolysis of the phosphaethynolate ion (PCO−). In this hydrolysis transformation, a new mechanism is proposed for the electrophilic reactivity of the...

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Veröffentlicht in:	Angewandte Chemie International Edition 2021-02, Vol.60 (7), p.3759-3767
Hauptverfasser:	Schreiber, Roy E., Goicoechea, Jose M.
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbon dioxide carbon dioxide activation Carboxylic acids Decarboxylation Esters Hydrolysis main-group elements Organic phosphorus Organic solvents phosphaethynolate Phosphine Phosphines Phosphorus Protonation reaction mechanisms
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