Redox-Induced Hydrogen Bond Reorientation Mimicking Electronic Coupling in Mixed-Valent Diruthenium and Macrocyclic Tetraruthenium Complexes

We present the coordination-driven self-assembly of three tetranuclear metallacycles containing intracyclic NH2, OH, or OMe functionalities through the combination of various isophthalic acid building blocks with a divinylphenylene diruthenium complex. All new complexes of this study were characteri...

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Veröffentlicht in:Inorganic chemistry 2020-11, Vol.59 (22), p.16703-16715
Hauptverfasser: Fink, Daniel, Staiger, Anne, Orth, Nicole, Linseis, Michael, Ivanović-Burmazović, Ivana, Winter, Rainer F
Format: Artikel
Sprache:eng
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