Computational Study on the Synergic Effect of Brønsted Acid and Hydrogen-Bonding Catalysis for the Dearomatization Reaction of Phenols with Diazo Functionality

Catalytic dearomative transformations of phenol variants via an ipso-Friedel-Crafts reaction could provide a straightforward method for the rapid assembly of functionalized spiromolecules as versatile synthetic scaffolds. We previously reported a dearomative spirocyclization reaction by merging Brøn...

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Veröffentlicht in:	Chemical & pharmaceutical bulletin 2020/11/01, Vol.68(11), pp.1104-1108
Hauptverfasser:	Yanagawa, Mai, Kobayashi, Mayu, Ikeda, Mitsuru, Harada, Shingo, Nemoto, Tetsuhiro
Format:	Artikel
Sprache:	eng
Schlagworte:	Acids Acids - chemistry Brønsted acid Catalysis Catalysts Computer applications Cyclization dearomatization Density Functional Theory Friedel-Crafts reaction Hydrogen Bonding Insertion Maleic acid phenol Phenols Phenols - chemistry Reaction mechanisms Spiro Compounds - chemistry spirocycle Sulfur Thiourea Thiourea - chemistry Thioureas
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