Metastable phase equilibrium during solid-state amorphization reaction of Zr-Co layers

The crystal-glass transition of Co--Zr layers via interdiffusion has been followed by Rutherford-backscattering spectrometry and X-ray-diffraction analysis. Thin-film multilayer samples of cobalt and Zr were annealed at 250 deg C for different times up to 21 h. Planar growth of the amorphous layer i...

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Veröffentlicht in:Physical review. B, Condensed matter Condensed matter, 1987-05, Vol.35 (13), p.7010-7014
Hauptverfasser: PAMPUS, K, BØTTIGER, J, TORP, B, SCHRÖDER, H, SAMWER, K
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container_end_page 7014
container_issue 13
container_start_page 7010
container_title Physical review. B, Condensed matter
container_volume 35
creator PAMPUS, K
BØTTIGER, J
TORP, B
SCHRÖDER, H
SAMWER, K
description The crystal-glass transition of Co--Zr layers via interdiffusion has been followed by Rutherford-backscattering spectrometry and X-ray-diffraction analysis. Thin-film multilayer samples of cobalt and Zr were annealed at 250 deg C for different times up to 21 h. Planar growth of the amorphous layer is observed. The changes in the concentration profiles, as observed with Rutherford-backscattering spectrometry, in combination with corresponding X-ray analysis, indicate an interstitial solid solution of approx = 3 at.% Co in crystalline Zr probably preceding the glass transition. This effect is discussed in the context of a metastable phase diagram. 23 ref.--AA
doi_str_mv 10.1103/PhysRevB.35.7010
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subjects Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science
rheology
Equations of state, phase equilibria, and phase transitions
Exact sciences and technology
Materials science
Metals, semimetals and alloys
Phase diagrams and microstructures developed by solidification and solid-solid phase transformations
Physics
Specific materials
Specific phase transitions
title Metastable phase equilibrium during solid-state amorphization reaction of Zr-Co layers
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