Two Mixed-Anion Units of [GeOSe3] and [GeO3S] Originating from Partial Isovalent Anion Substitution and Inducing Moderate Second Harmonic Generation Response and Large Birefringence

Highly polarizable mixed-anion structural building units (SBUs) have been demonstrated as promising candidates for high-performing optical crystals. In this work, two new mixed-anion SBUs of [GeOSe3] and [GeO3S] are first designed through partial isovalent substitution of chalcogen atoms by O atoms...

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Veröffentlicht in:Inorganic chemistry 2020-11, Vol.59 (22), p.16716-16724
Hauptverfasser: Xing, Wenhao, Fang, Pan, Wang, Naizheng, Li, Zhuang, Lin, Zheshuai, Yao, Jiyong, Yin, Wenlong, Kang, Bin
Format: Artikel
Sprache:eng
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