Hexavanadate–Organogold(I) Hybrid Compounds: Synthesis by the Azide–Alkyne Cycloaddition and Density Functional Theory Study of an Intriguing Electron Density Distribution
The fully oxidized Lindqvist-type hexavanadate compounds decorated by phosphine-derivatized Au(I) moieties oriented in a transoid fashion (n-Bu4N)2[V6O13{(OCH2)3CCH2(N3C2C6H5)AuP(C6H4OMe)3}2] (POM N Au ) and (n-Bu4N)2[V6O13{(OCH2)3CCH2OCH2(C2N3H)AuP(C6H4OMe)3}2] (POM C Au ) have been prepared b...
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| Veröffentlicht in: | Inorganic chemistry 2020-11, Vol.59 (22), p.16122-16126 |
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| container_title | Inorganic chemistry |
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| creator | Petrovskii, Stanislav K Khistiaeva, Viktoria V Sizova, Anastasia A Sizov, Vladimir V Paderina, Aleksandra V Koshevoy, Igor O Monakhov, Kirill Yu Grachova, Elena V |
| description | The fully oxidized Lindqvist-type hexavanadate compounds decorated by phosphine-derivatized Au(I) moieties oriented in a transoid fashion (n-Bu4N)2[V6O13{(OCH2)3CCH2(N3C2C6H5)AuP(C6H4OMe)3}2] (POM N Au ) and (n-Bu4N)2[V6O13{(OCH2)3CCH2OCH2(C2N3H)AuP(C6H4OMe)3}2] (POM C Au ) have been prepared by azide–alkyne cycloaddition reactions and characterized by various techniques, including NMR, IR, and UV/vis spectroscopy and electrospray ionization mass spectrometry. Electronic structure calculations unveil the potential of these model hybrid junctions for application in controlled charge-transport experiments on substrate surfaces. |
| doi_str_mv | 10.1021/acs.inorgchem.0c02621 |
| format | Article |
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Chem</addtitle><date>2020-11-16</date><risdate>2020</risdate><volume>59</volume><issue>22</issue><spage>16122</spage><epage>16126</epage><pages>16122-16126</pages><issn>0020-1669</issn><eissn>1520-510X</eissn><abstract>The fully oxidized Lindqvist-type hexavanadate compounds decorated by phosphine-derivatized Au(I) moieties oriented in a transoid fashion (n-Bu4N)2[V6O13{(OCH2)3CCH2(N3C2C6H5)AuP(C6H4OMe)3}2] (POM N Au ) and (n-Bu4N)2[V6O13{(OCH2)3CCH2OCH2(C2N3H)AuP(C6H4OMe)3}2] (POM C Au ) have been prepared by azide–alkyne cycloaddition reactions and characterized by various techniques, including NMR, IR, and UV/vis spectroscopy and electrospray ionization mass spectrometry. 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| title | Hexavanadate–Organogold(I) Hybrid Compounds: Synthesis by the Azide–Alkyne Cycloaddition and Density Functional Theory Study of an Intriguing Electron Density Distribution |
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