Nuclear Resonance Vibrational Spectroscopic Definition of the Facial Triad FeIVO Intermediate in Taurine Dioxygenase: Evaluation of Structural Contributions to Hydrogen Atom Abstraction

The α-ketoglutarate (αKG)-dependent oxygenases catalyze a diverse range of chemical reactions using a common high-spin FeIVO intermediate that, in most reactions, abstract a hydrogen atom from the substrate. Previously, the FeIVO intermediate in the αKG-dependent halogenase SyrB2 was characterized...

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Veröffentlicht in:	Journal of the American Chemical Society 2020-11, Vol.142 (44), p.18886-18896
Hauptverfasser:	Srnec, Martin, Iyer, Shyam R, Dassama, Laura M. K, Park, Kiyoung, Wong, Shaun D, Sutherlin, Kyle D, Yoda, Yoshitaka, Kobayashi, Yasuhiro, Kurokuzu, Masayuki, Saito, Makina, Seto, Makoto, Krebs, Carsten, Bollinger, J. Martin, Solomon, Edward I
Format:	Artikel
Sprache:	eng
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