Nb2O5 nanoparticles decorated with magnetic ferrites for wastewater photocatalytic remediation
Nanotechnology has been studied on environmental remediation processes to foster greater photocatalysts efficiency and reuse in wastewater. This study investigated the photocatalytic efficiency and viability of niobium pentoxide (Nb 2 O 5 ) nanoparticles decorated with magnetic ferrite (cobalt ferri...
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| Veröffentlicht in: | Environmental science and pollution research international 2021-05, Vol.28 (19), p.23731-23741 |
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| creator | Paris, Elaine Cristina Malafatti, João Otávio Donizette Sciena, Camila Rodrigues Junior, Luiz Ferreira Neves Zenatti, Alessandra Escote, Márcia Tsuyama Moreira, Ailton José Freschi, Gian Paulo Giovanni |
| description | Nanotechnology has been studied on environmental remediation processes to foster greater photocatalysts efficiency and reuse in wastewater. This study investigated the photocatalytic efficiency and viability of niobium pentoxide (Nb
2
O
5
) nanoparticles decorated with magnetic ferrite (cobalt ferrite (CoFe
2
O
4
) or magnesium ferrite (MgFe
2
O
4
)) for atrazine photodegradation. Thus, the decorated Nb
2
O
5
was synthesized by the polymeric precursor method, forming nanoparticles with sizes ranging from 25 to 50 nm. Nanocomposite elementary analyses showed a homogeneous distribution of elements on all particles surface. Efficient magnetic saturation was observed for pure CoFe
2
O
4
(53 emu g
−1
) and MgFe
2
O
4
(19 emu g
−1
) nanoparticles, promoting the magnetic removal of Nb
2
O
5
:CoFe
2
O
4
and Nb
2
O
5
:MgFe
2
O
4
nanocomposites. Photocatalytic assays showed 88% efficiency for atrazine photodegradation with all nanomaterials, which represented a 21% increase compared to photolysis in the 1st cycle. The magnetic nanocomposites when applied to a 5th cycle maintained the atrazine photodegradation activity. In this way, magnetic Nb
2
O
5
-based nanocomposites decorated with ferrite nanoparticles showed an efficient photocatalytic response, in addition to posterior magnetic removal from the aqueous medium. Therefore, the evaluated magnetic Nb
2
O
5
nanocomposites may be an alternative to enhance the wastewater removal process and foster the reuse in advanced oxidative processes. |
| doi_str_mv | 10.1007/s11356-020-11262-5 |
| format | Article |
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2
O
5
) nanoparticles decorated with magnetic ferrite (cobalt ferrite (CoFe
2
O
4
) or magnesium ferrite (MgFe
2
O
4
)) for atrazine photodegradation. Thus, the decorated Nb
2
O
5
was synthesized by the polymeric precursor method, forming nanoparticles with sizes ranging from 25 to 50 nm. Nanocomposite elementary analyses showed a homogeneous distribution of elements on all particles surface. Efficient magnetic saturation was observed for pure CoFe
2
O
4
(53 emu g
−1
) and MgFe
2
O
4
(19 emu g
−1
) nanoparticles, promoting the magnetic removal of Nb
2
O
5
:CoFe
2
O
4
and Nb
2
O
5
:MgFe
2
O
4
nanocomposites. Photocatalytic assays showed 88% efficiency for atrazine photodegradation with all nanomaterials, which represented a 21% increase compared to photolysis in the 1st cycle. The magnetic nanocomposites when applied to a 5th cycle maintained the atrazine photodegradation activity. In this way, magnetic Nb
2
O
5
-based nanocomposites decorated with ferrite nanoparticles showed an efficient photocatalytic response, in addition to posterior magnetic removal from the aqueous medium. Therefore, the evaluated magnetic Nb
2
O
5
nanocomposites may be an alternative to enhance the wastewater removal process and foster the reuse in advanced oxidative processes.</description><identifier>ISSN: 0944-1344</identifier><identifier>EISSN: 1614-7499</identifier><identifier>DOI: 10.1007/s11356-020-11262-5</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Advanced Oxidation/Reduction Technologies: An Perspective from Iberoamerican Countries ; Aquatic Pollution ; Aqueous solutions ; Atmospheric Protection/Air Quality Control/Air Pollution ; Atrazine ; Cobalt ; Cobalt ferrites ; Decoration ; Earth and Environmental Science ; Ecotoxicology ; Efficiency ; Environment ; Environmental Chemistry ; Environmental cleanup ; Environmental Health ; Environmental science ; Herbicides ; Magnesium ; Magnesium ferrites ; Magnetic saturation ; Nanocomposites ; Nanomaterials ; Nanoparticles ; Nanotechnology ; Niobium ; Niobium oxides ; Photocatalysis ; Photodegradation ; Photolysis ; Prepolymers ; Remediation ; Waste Water Technology ; Wastewater ; Wastewater treatment ; Water Management ; Water Pollution Control</subject><ispartof>Environmental science and pollution research international, 2021-05, Vol.28 (19), p.23731-23741</ispartof><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2020</rights><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c389t-af607038da9988b468d9ee04140ae32e90de2164c8b3dfd54209084ea88a764d3</citedby><cites>FETCH-LOGICAL-c389t-af607038da9988b468d9ee04140ae32e90de2164c8b3dfd54209084ea88a764d3</cites><orcidid>0000-0001-8599-9674</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11356-020-11262-5$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11356-020-11262-5$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Paris, Elaine Cristina</creatorcontrib><creatorcontrib>Malafatti, João Otávio Donizette</creatorcontrib><creatorcontrib>Sciena, Camila Rodrigues</creatorcontrib><creatorcontrib>Junior, Luiz Ferreira Neves</creatorcontrib><creatorcontrib>Zenatti, Alessandra</creatorcontrib><creatorcontrib>Escote, Márcia Tsuyama</creatorcontrib><creatorcontrib>Moreira, Ailton José</creatorcontrib><creatorcontrib>Freschi, Gian Paulo Giovanni</creatorcontrib><title>Nb2O5 nanoparticles decorated with magnetic ferrites for wastewater photocatalytic remediation</title><title>Environmental science and pollution research international</title><addtitle>Environ Sci Pollut Res</addtitle><description>Nanotechnology has been studied on environmental remediation processes to foster greater photocatalysts efficiency and reuse in wastewater. This study investigated the photocatalytic efficiency and viability of niobium pentoxide (Nb
2
O
5
) nanoparticles decorated with magnetic ferrite (cobalt ferrite (CoFe
2
O
4
) or magnesium ferrite (MgFe
2
O
4
)) for atrazine photodegradation. Thus, the decorated Nb
2
O
5
was synthesized by the polymeric precursor method, forming nanoparticles with sizes ranging from 25 to 50 nm. Nanocomposite elementary analyses showed a homogeneous distribution of elements on all particles surface. Efficient magnetic saturation was observed for pure CoFe
2
O
4
(53 emu g
−1
) and MgFe
2
O
4
(19 emu g
−1
) nanoparticles, promoting the magnetic removal of Nb
2
O
5
:CoFe
2
O
4
and Nb
2
O
5
:MgFe
2
O
4
nanocomposites. Photocatalytic assays showed 88% efficiency for atrazine photodegradation with all nanomaterials, which represented a 21% increase compared to photolysis in the 1st cycle. The magnetic nanocomposites when applied to a 5th cycle maintained the atrazine photodegradation activity. In this way, magnetic Nb
2
O
5
-based nanocomposites decorated with ferrite nanoparticles showed an efficient photocatalytic response, in addition to posterior magnetic removal from the aqueous medium. Therefore, the evaluated magnetic Nb
2
O
5
nanocomposites may be an alternative to enhance the wastewater removal process and foster the reuse in advanced oxidative processes.</description><subject>Advanced Oxidation/Reduction Technologies: An Perspective from Iberoamerican Countries</subject><subject>Aquatic Pollution</subject><subject>Aqueous solutions</subject><subject>Atmospheric Protection/Air Quality Control/Air Pollution</subject><subject>Atrazine</subject><subject>Cobalt</subject><subject>Cobalt ferrites</subject><subject>Decoration</subject><subject>Earth and Environmental Science</subject><subject>Ecotoxicology</subject><subject>Efficiency</subject><subject>Environment</subject><subject>Environmental Chemistry</subject><subject>Environmental cleanup</subject><subject>Environmental Health</subject><subject>Environmental science</subject><subject>Herbicides</subject><subject>Magnesium</subject><subject>Magnesium ferrites</subject><subject>Magnetic saturation</subject><subject>Nanocomposites</subject><subject>Nanomaterials</subject><subject>Nanoparticles</subject><subject>Nanotechnology</subject><subject>Niobium</subject><subject>Niobium oxides</subject><subject>Photocatalysis</subject><subject>Photodegradation</subject><subject>Photolysis</subject><subject>Prepolymers</subject><subject>Remediation</subject><subject>Waste Water Technology</subject><subject>Wastewater</subject><subject>Wastewater treatment</subject><subject>Water Management</subject><subject>Water Pollution Control</subject><issn>0944-1344</issn><issn>1614-7499</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp9kEtLAzEUhYMoWB9_wNWAGzfRvCaTLKX4gmI3ujWkkzvtlOlkTFJK_72pIwguXN3F_c7h8CF0RcktJaS6i5TyUmLCCKaUSYbLIzShkgpcCa2P0YRoITDlQpyisxjXJJOaVRP08bpg87Lobe8HG1JbdxALB7UPNoErdm1aFRu77CG_igZCaFMGGh-KnY0JdpkKxbDyydc22W5_wAJswLU2tb6_QCeN7SJc_txz9P748DZ9xrP508v0foZrrnTCtpGkIlw5q7VSCyGV0wBEUEEscAaaOGBUilotuGtcKfJ6ogRYpWwlhePn6GbsHYL_3EJMZtPGGrrO9uC30TBRiiyGsSqj13_Qtd-GPq8zrORUMEk1yRQbqTr4GAM0Zgjtxoa9ocQclJtRuckizbdyU-YQH0Mxw_0Swm_1P6kv8cmEVg</recordid><startdate>20210501</startdate><enddate>20210501</enddate><creator>Paris, Elaine Cristina</creator><creator>Malafatti, João Otávio Donizette</creator><creator>Sciena, Camila Rodrigues</creator><creator>Junior, Luiz Ferreira Neves</creator><creator>Zenatti, Alessandra</creator><creator>Escote, Márcia Tsuyama</creator><creator>Moreira, Ailton 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nanoparticles decorated with magnetic ferrites for wastewater photocatalytic remediation</title><author>Paris, Elaine Cristina ; Malafatti, João Otávio Donizette ; Sciena, Camila Rodrigues ; Junior, Luiz Ferreira Neves ; Zenatti, Alessandra ; Escote, Márcia Tsuyama ; Moreira, Ailton José ; Freschi, Gian Paulo Giovanni</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c389t-af607038da9988b468d9ee04140ae32e90de2164c8b3dfd54209084ea88a764d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Advanced Oxidation/Reduction Technologies: An Perspective from Iberoamerican Countries</topic><topic>Aquatic Pollution</topic><topic>Aqueous solutions</topic><topic>Atmospheric Protection/Air Quality Control/Air Pollution</topic><topic>Atrazine</topic><topic>Cobalt</topic><topic>Cobalt ferrites</topic><topic>Decoration</topic><topic>Earth and Environmental Science</topic><topic>Ecotoxicology</topic><topic>Efficiency</topic><topic>Environment</topic><topic>Environmental Chemistry</topic><topic>Environmental cleanup</topic><topic>Environmental Health</topic><topic>Environmental science</topic><topic>Herbicides</topic><topic>Magnesium</topic><topic>Magnesium ferrites</topic><topic>Magnetic saturation</topic><topic>Nanocomposites</topic><topic>Nanomaterials</topic><topic>Nanoparticles</topic><topic>Nanotechnology</topic><topic>Niobium</topic><topic>Niobium oxides</topic><topic>Photocatalysis</topic><topic>Photodegradation</topic><topic>Photolysis</topic><topic>Prepolymers</topic><topic>Remediation</topic><topic>Waste Water Technology</topic><topic>Wastewater</topic><topic>Wastewater treatment</topic><topic>Water Management</topic><topic>Water Pollution Control</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Paris, Elaine Cristina</creatorcontrib><creatorcontrib>Malafatti, João Otávio 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Rodrigues</au><au>Junior, Luiz Ferreira Neves</au><au>Zenatti, Alessandra</au><au>Escote, Márcia Tsuyama</au><au>Moreira, Ailton José</au><au>Freschi, Gian Paulo Giovanni</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Nb2O5 nanoparticles decorated with magnetic ferrites for wastewater photocatalytic remediation</atitle><jtitle>Environmental science and pollution research international</jtitle><stitle>Environ Sci Pollut Res</stitle><date>2021-05-01</date><risdate>2021</risdate><volume>28</volume><issue>19</issue><spage>23731</spage><epage>23741</epage><pages>23731-23741</pages><issn>0944-1344</issn><eissn>1614-7499</eissn><abstract>Nanotechnology has been studied on environmental remediation processes to foster greater photocatalysts efficiency and reuse in wastewater. This study investigated the photocatalytic efficiency and viability of niobium pentoxide (Nb
2
O
5
) nanoparticles decorated with magnetic ferrite (cobalt ferrite (CoFe
2
O
4
) or magnesium ferrite (MgFe
2
O
4
)) for atrazine photodegradation. Thus, the decorated Nb
2
O
5
was synthesized by the polymeric precursor method, forming nanoparticles with sizes ranging from 25 to 50 nm. Nanocomposite elementary analyses showed a homogeneous distribution of elements on all particles surface. Efficient magnetic saturation was observed for pure CoFe
2
O
4
(53 emu g
−1
) and MgFe
2
O
4
(19 emu g
−1
) nanoparticles, promoting the magnetic removal of Nb
2
O
5
:CoFe
2
O
4
and Nb
2
O
5
:MgFe
2
O
4
nanocomposites. Photocatalytic assays showed 88% efficiency for atrazine photodegradation with all nanomaterials, which represented a 21% increase compared to photolysis in the 1st cycle. The magnetic nanocomposites when applied to a 5th cycle maintained the atrazine photodegradation activity. In this way, magnetic Nb
2
O
5
-based nanocomposites decorated with ferrite nanoparticles showed an efficient photocatalytic response, in addition to posterior magnetic removal from the aqueous medium. Therefore, the evaluated magnetic Nb
2
O
5
nanocomposites may be an alternative to enhance the wastewater removal process and foster the reuse in advanced oxidative processes.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s11356-020-11262-5</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0001-8599-9674</orcidid></addata></record> |
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| ispartof | Environmental science and pollution research international, 2021-05, Vol.28 (19), p.23731-23741 |
| issn | 0944-1344 1614-7499 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_2454112227 |
| source | SpringerLink Journals |
| subjects | Advanced Oxidation/Reduction Technologies: An Perspective from Iberoamerican Countries Aquatic Pollution Aqueous solutions Atmospheric Protection/Air Quality Control/Air Pollution Atrazine Cobalt Cobalt ferrites Decoration Earth and Environmental Science Ecotoxicology Efficiency Environment Environmental Chemistry Environmental cleanup Environmental Health Environmental science Herbicides Magnesium Magnesium ferrites Magnetic saturation Nanocomposites Nanomaterials Nanoparticles Nanotechnology Niobium Niobium oxides Photocatalysis Photodegradation Photolysis Prepolymers Remediation Waste Water Technology Wastewater Wastewater treatment Water Management Water Pollution Control |
| title | Nb2O5 nanoparticles decorated with magnetic ferrites for wastewater photocatalytic remediation |
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