Highly Emissive Perylene Diimide-Based Metallacages and Their Host–Guest Chemistry for Information Encryption
Here we report two highly emissive perylene diimide (PDI)-based metallacages and explore their complexation with polycyclic aromatic hydrocarbons, such as pyrene, triphenylene, and perylene. The fluorescence quantum yields of metallacages exceed 90% and their binding constants with perylene can reac...
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| Veröffentlicht in: | Journal of the American Chemical Society 2020-11, Vol.142 (44), p.18763-18768 |
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| container_end_page | 18768 |
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| container_issue | 44 |
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| container_title | Journal of the American Chemical Society |
| container_volume | 142 |
| creator | Hou, Yali Zhang, Zeyuan Lu, Shuai Yuan, Jun Zhu, Qiangyu Chen, Wei-Peng Ling, Sanliang Li, Xiaopeng Zheng, Yan-Zhen Zhu, Kelong Zhang, Mingming |
| description | Here we report two highly emissive perylene diimide (PDI)-based metallacages and explore their complexation with polycyclic aromatic hydrocarbons, such as pyrene, triphenylene, and perylene. The fluorescence quantum yields of metallacages exceed 90% and their binding constants with perylene can reach as high as 2.41 × 104 M–1 in acetonitrile. These features enable further tuning of the emission of the host–guest complexes to obtain white-light emission based on the complementary orange emission of the metallacages and the blue emission of perylene. Moreover, owing to the huge differences of their quantum yields in solution and in the solid state, the host–guest complexes are successfully employed for information encryption. This study offers a general approach for the construction of emissive metallacages and explores their application for information encryption. |
| doi_str_mv | 10.1021/jacs.0c09904 |
| format | Article |
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| source | ACS Publications |
| title | Highly Emissive Perylene Diimide-Based Metallacages and Their Host–Guest Chemistry for Information Encryption |
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