Photochemical Radical C–H Halogenation of Benzyl N‐Methyliminodiacetyl (MIDA) Boronates: Synthesis of α‐Functionalized Alkyl Boronates

α‐Haloboronates are useful organic synthons that can be converted to a diverse array of α‐substituted alkyl borons. Methods to α‐haloboronates are limiting and often suffer from harsh reaction conditions. Reported herein is a photochemical radical C‐H halogenation of benzyl N‐methyliminodiacetyl (MI...

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Veröffentlicht in:	Angewandte Chemie International Edition 2021-02, Vol.60 (7), p.3454-3458
Hauptverfasser:	Yang, Ling, Tan, Dong‐Hang, Fan, Wen‐Xin, Liu, Xu‐Ge, Wu, Jia‐Qiang, Huang, Zhi‐Shu, Li, Qingjiang, Wang, Honggen
Format:	Artikel
Sprache:	eng
Schlagworte:	Bromination Esters Fluorination Halogenation ketone catalysis Nucleophiles organoboron Photochemicals photochemistry radical reaction
Online-Zugang:	Volltext
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