Iminophosphorano‐Substituted Bispyridinylidenes: Redox Potentials and Substituent Constants from Tolman Electronic Parameters

Bispyridinylidenes (BPYs) have emerged as an important class of neutral organic electron donors, with redox potentials that vary widely with choice of substituent. Methods to predict the effect of substitution on the redox potential are therefore highly desirable. Here we show that the redox potenti...

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Veröffentlicht in:	Chemistry : a European journal 2020-12, Vol.26 (72), p.17371-17375
Hauptverfasser:	Richard, Nicholas A., Khor, Chun Keat, Hetherington, Sydney M., Mills, Scott L., Decken, Andreas, Dyker, C. Adam
Format:	Artikel
Sprache:	eng
Schlagworte:	bispyridinylidene Chemistry Donors (electronic) Electrode potentials organic electron donor Parameters Phosphine Phosphines Redox potential substituent constant Substitutes tolman electronic parameter
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