PtCl2 mediated peripheral transformation of carbatriphyrin(3.1.1) into a meso-fused β–β′ dimer and its monomer analogue

PtCl2 mediated peripheral transformation of carbatriphyrin(3.1.1) into a meso-fused β–β′ dimer and its monomer analogue

An unprecedented formation of a meso-fused β–β′ carbaporphyrin dimer and its monomer with a keto group was described. These analogues were synthesized from carbatriphyrin(3.1.1.) by a metal assisted strategy using PtCl2 salt in a single step without any prefunctionalized precursors. Upon dimerizatio...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2020-10, Vol.56 (84), p.12809-12812
Hauptverfasser: Murugavel, M, Adinarayana, B, Das, Mainak, Peruncheralathan, S, Narasinga Rao Palepu, Srinivasan, A
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Crystallography
Dimerization
Dimers
Monomers
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container_end_page 12812
container_issue 84
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container_title Chemical communications (Cambridge, England)
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creator Murugavel, M
Adinarayana, B
Das, Mainak
Peruncheralathan, S
Narasinga Rao Palepu
Srinivasan, A
description An unprecedented formation of a meso-fused β–β′ carbaporphyrin dimer and its monomer with a keto group was described. These analogues were synthesized from carbatriphyrin(3.1.1.) by a metal assisted strategy using PtCl2 salt in a single step without any prefunctionalized precursors. Upon dimerization, the monomeric ligand with a dianionic core is transformed into a dimeric structure with unique trianionic cores.
doi_str_mv 10.1039/d0cc05309k
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source Royal Society Of Chemistry Journals; Alma/SFX Local Collection
subjects Crystallography
Dimerization
Dimers
Monomers
title PtCl2 mediated peripheral transformation of carbatriphyrin(3.1.1) into a meso-fused β–β′ dimer and its monomer analogue
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