Single-Step Glycosylations with 13 C-Labelled Sulfoxide Donors: A Low-Temperature NMR Cartography of the Distinguishing Mechanistic Intermediates

Glycosyl sulfoxides have gained recognition in the total synthesis of complex oligosaccharides and as model substrates for dissecting the mechanisms involved. Reactions of these donors are usually performed under pre-activation conditions, but an experimentally more convenient single-step protocol h...

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Veröffentlicht in:	Chemistry : a European journal 2021-01, Vol.27 (6), p.2030-2042
Hauptverfasser:	Santana, Andrés G, Montalvillo-Jiménez, Laura, Díaz-Casado, Laura, Mann, Enrique, Jiménez-Barbero, Jesús, Gómez, Ana M, Asensio, Juan Luis
Format:	Artikel
Sprache:	eng
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