Determination of phase composition of silicon nitride powders by silicon-29 magic angle spinning nuclear magnetic resonance spectroscopy
The use of solid-state exp 29 Si NMR spectroscopy to analyze Si sub 3 N sub 4 powders is demonstrated for a series of commercial and research samples. In particular, two different commercial powders contain 20 and 30% amorphous Si sub 3 N sub 4 content, as identified by the application of methods de...
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| Veröffentlicht in: | Anal. Chem.; (United States) 1987-12, Vol.59 (23), p.2794-2797 |
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| container_issue | 23 |
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| container_title | Anal. Chem.; (United States) |
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| creator | Carduner, Keith R Carter, R. O Milberg, M. E Crosbie, G. M |
| description | The use of solid-state exp 29 Si NMR spectroscopy to analyze Si sub 3 N sub 4 powders is demonstrated for a series of commercial and research samples. In particular, two different commercial powders contain 20 and 30% amorphous Si sub 3 N sub 4 content, as identified by the application of methods described. These same materials had been analyzed by X-ray diffraction as only crystalline Si sub 3 N sub 4 . NMR spectroscopy is capable of distinguishing among different amorphous Si species normally found in preparations of Si sub 3 N sub 4 powders. These include amorphous Si sub 3 N sub 4 , silicon oxynitrides, silicates, and elemental Si. The measurement of concentration of these species is made for correlation with properties of powder sinterability. 18 ref.--AA |
| doi_str_mv | 10.1021/ac00150a015 |
| format | Article |
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The measurement of concentration of these species is made for correlation with properties of powder sinterability. 18 ref.--AA</description><identifier>ISSN: 0003-2700</identifier><identifier>EISSN: 1520-6882</identifier><identifier>DOI: 10.1021/ac00150a015</identifier><identifier>CODEN: ANCHAM</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>360602 - Other Materials- Structure & Phase Studies ; 400201 - Chemical & Physicochemical Properties ; Applied sciences ; Building materials. Ceramics. 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O</creatorcontrib><creatorcontrib>Milberg, M. E</creatorcontrib><creatorcontrib>Crosbie, G. M</creatorcontrib><creatorcontrib>Ford Motor Company, Dearborn, MI</creatorcontrib><title>Determination of phase composition of silicon nitride powders by silicon-29 magic angle spinning nuclear magnetic resonance spectroscopy</title><title>Anal. Chem.; (United States)</title><addtitle>Anal. Chem</addtitle><description>The use of solid-state exp 29 Si NMR spectroscopy to analyze Si sub 3 N sub 4 powders is demonstrated for a series of commercial and research samples. In particular, two different commercial powders contain 20 and 30% amorphous Si sub 3 N sub 4 content, as identified by the application of methods described. These same materials had been analyzed by X-ray diffraction as only crystalline Si sub 3 N sub 4 . NMR spectroscopy is capable of distinguishing among different amorphous Si species normally found in preparations of Si sub 3 N sub 4 powders. These include amorphous Si sub 3 N sub 4 , silicon oxynitrides, silicates, and elemental Si. The measurement of concentration of these species is made for correlation with properties of powder sinterability. 18 ref.--AA</description><subject>360602 - Other Materials- Structure & Phase Studies</subject><subject>400201 - Chemical & Physicochemical Properties</subject><subject>Applied sciences</subject><subject>Building materials. Ceramics. Glasses</subject><subject>Chemical industry and chemicals</subject><subject>DATA</subject><subject>EVEN-ODD NUCLEI</subject><subject>Exact sciences and technology</subject><subject>EXPERIMENTAL DATA</subject><subject>INFORMATION</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>ISOTOPES</subject><subject>LIGHT NUCLEI</subject><subject>MAGNETIC RESONANCE</subject><subject>MATERIALS SCIENCE</subject><subject>NITRIDES</subject><subject>NITROGEN COMPOUNDS</subject><subject>NMR SPECTRA</subject><subject>NUCLEAR MAGNETIC RESONANCE</subject><subject>NUCLEI</subject><subject>NUMERICAL DATA</subject><subject>PHASE STUDIES</subject><subject>PNICTIDES</subject><subject>POWDERS</subject><subject>Refractory products</subject><subject>RESONANCE</subject><subject>SILICON 29</subject><subject>SILICON COMPOUNDS</subject><subject>SILICON ISOTOPES</subject><subject>SILICON NITRIDES</subject><subject>Special refractories</subject><subject>SPECTRA</subject><subject>STABLE ISOTOPES</subject><issn>0003-2700</issn><issn>1520-6882</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1987</creationdate><recordtype>article</recordtype><recordid>eNqNkc9u1DAQxiMEEkvhxAtECMEBBcZ24sRHKH-lFVRQztasd7J1SezUkxXsG_DYeJW24sCBi23N9_Po-2aK4rGAlwKkeIUOQDSA-bhTrEQjodJdJ-8WKwBQlWwB7hcPmC8zJkDoVfH7Lc2URh9w9jGUsS-nC2QqXRynyP6myH7wLj-Dn5PfUjnFn1tKXG4ON1IlTTnizrsSw26gkicfgg-7MuzdQJiOYqA564k4BgzuyJCbU2QXp8PD4l6PA9Oj6_uk-P7-3fnpx2r95cOn09frCpWq58oJ04u-kz3ARkvstJQGenIblfO4rdBGQkPQtkBKYYMt1GB6VSt0W202Up0UT5a-kWdv2fmZ3EX2H7IV29TCyNpk6NkCTSle7YlnO3p2NAwYKO7ZyrqulTHwP6ASutMZfLGALuflRL2dkh8xHawAe9yd_Wt3mX563RbZ4dCnPC7Pt1_aru40iIxVC-Z5pl-3MqYfVreqbez52Tf79fNanok3rT3Ger7w6Nhexn0KedL_NPAHw321Uw</recordid><startdate>19871201</startdate><enddate>19871201</enddate><creator>Carduner, Keith R</creator><creator>Carter, R. 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M</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a334t-c19f1f82f00b62a862290fecb3101cd169205e0770e33a5a70409f343acd69b23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1987</creationdate><topic>360602 - Other Materials- Structure & Phase Studies</topic><topic>400201 - Chemical & Physicochemical Properties</topic><topic>Applied sciences</topic><topic>Building materials. Ceramics. Glasses</topic><topic>Chemical industry and chemicals</topic><topic>DATA</topic><topic>EVEN-ODD NUCLEI</topic><topic>Exact sciences and technology</topic><topic>EXPERIMENTAL DATA</topic><topic>INFORMATION</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>ISOTOPES</topic><topic>LIGHT NUCLEI</topic><topic>MAGNETIC RESONANCE</topic><topic>MATERIALS SCIENCE</topic><topic>NITRIDES</topic><topic>NITROGEN COMPOUNDS</topic><topic>NMR SPECTRA</topic><topic>NUCLEAR MAGNETIC RESONANCE</topic><topic>NUCLEI</topic><topic>NUMERICAL DATA</topic><topic>PHASE STUDIES</topic><topic>PNICTIDES</topic><topic>POWDERS</topic><topic>Refractory products</topic><topic>RESONANCE</topic><topic>SILICON 29</topic><topic>SILICON COMPOUNDS</topic><topic>SILICON ISOTOPES</topic><topic>SILICON NITRIDES</topic><topic>Special refractories</topic><topic>SPECTRA</topic><topic>STABLE ISOTOPES</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Carduner, Keith R</creatorcontrib><creatorcontrib>Carter, R. 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M</au><aucorp>Ford Motor Company, Dearborn, MI</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Determination of phase composition of silicon nitride powders by silicon-29 magic angle spinning nuclear magnetic resonance spectroscopy</atitle><jtitle>Anal. Chem.; (United States)</jtitle><addtitle>Anal. Chem</addtitle><date>1987-12-01</date><risdate>1987</risdate><volume>59</volume><issue>23</issue><spage>2794</spage><epage>2797</epage><pages>2794-2797</pages><issn>0003-2700</issn><eissn>1520-6882</eissn><coden>ANCHAM</coden><abstract>The use of solid-state exp 29 Si NMR spectroscopy to analyze Si sub 3 N sub 4 powders is demonstrated for a series of commercial and research samples. In particular, two different commercial powders contain 20 and 30% amorphous Si sub 3 N sub 4 content, as identified by the application of methods described. These same materials had been analyzed by X-ray diffraction as only crystalline Si sub 3 N sub 4 . NMR spectroscopy is capable of distinguishing among different amorphous Si species normally found in preparations of Si sub 3 N sub 4 powders. These include amorphous Si sub 3 N sub 4 , silicon oxynitrides, silicates, and elemental Si. The measurement of concentration of these species is made for correlation with properties of powder sinterability. 18 ref.--AA</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/ac00150a015</doi><tpages>4</tpages></addata></record> |
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| ispartof | Anal. Chem.; (United States), 1987-12, Vol.59 (23), p.2794-2797 |
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| source | American Chemical Society Journals |
| subjects | 360602 - Other Materials- Structure & Phase Studies 400201 - Chemical & Physicochemical Properties Applied sciences Building materials. Ceramics. Glasses Chemical industry and chemicals DATA EVEN-ODD NUCLEI Exact sciences and technology EXPERIMENTAL DATA INFORMATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ISOTOPES LIGHT NUCLEI MAGNETIC RESONANCE MATERIALS SCIENCE NITRIDES NITROGEN COMPOUNDS NMR SPECTRA NUCLEAR MAGNETIC RESONANCE NUCLEI NUMERICAL DATA PHASE STUDIES PNICTIDES POWDERS Refractory products RESONANCE SILICON 29 SILICON COMPOUNDS SILICON ISOTOPES SILICON NITRIDES Special refractories SPECTRA STABLE ISOTOPES |
| title | Determination of phase composition of silicon nitride powders by silicon-29 magic angle spinning nuclear magnetic resonance spectroscopy |
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