Synthesis of Acyl Fluorides via DAST-Mediated Fluorinative C–C Bond Cleavage of Activated Ketones

A new protocol for preparation of acyl fluorides was developed by recognizing activated ketones as starting materials. The method provides a different scope compared with previously reported methods that employ carboxylic acids as substrates. A working hypothesis of pull-and-push-driven fluorinative...

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Veröffentlicht in:	Organic letters 2020-10, Vol.22 (19), p.7465-7469
Hauptverfasser:	Kim, Danhee, Lim, Hee Nam
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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