A Simple and Effective Method for Speciation Analysis of 13 Arsenic Species Using HPLC on a Fluorocarbon Stationary Phase Coupled to ICP-MS
The separation properties of arsenic species was investigated using HPLC-ICP-MS with several commercially available fluorocarbon stationary phases and no ion-pair reagents in HPLC. One pentafluorophenyl column showed the highest potential for the separation of a larger number of arsenic species when...
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| Veröffentlicht in: | Analytical Sciences 2021/02/10, Vol.37(2), pp.381-386 |
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| creator | MIYASHITA, Shin-ichi KINOSHITA, Kenji KAISE, Toshikazu |
| description | The separation properties of arsenic species was investigated using HPLC-ICP-MS with several commercially available fluorocarbon stationary phases and no ion-pair reagents in HPLC. One pentafluorophenyl column showed the highest potential for the separation of a larger number of arsenic species when using simple acid-based mobile phases. After modification of the operational parameters in HPLC, the speciation analysis of 13 representative arsenic species: arsenite, arsenate, methylarsonic acid, dimethylarsinic acid, trimethylarsine oxide, tetramethylarsonium, arsenobetaine, arsenocholine, thio-dimethylarsinic acid, oxo-arsenosugar-glycerol, oxo-arsenosugar-phosphate, oxo-arsenosugar-sulfonate, and oxo-arsenosugar-sulfate, was achieved by HPLC-ICP-MS with the column along with a mobile phase of 0.05% heptafluorobutyric acid–methanol (99:1, volume per volume). |
| doi_str_mv | 10.2116/analsci.20N019 |
| format | Article |
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One pentafluorophenyl column showed the highest potential for the separation of a larger number of arsenic species when using simple acid-based mobile phases. After modification of the operational parameters in HPLC, the speciation analysis of 13 representative arsenic species: arsenite, arsenate, methylarsonic acid, dimethylarsinic acid, trimethylarsine oxide, tetramethylarsonium, arsenobetaine, arsenocholine, thio-dimethylarsinic acid, oxo-arsenosugar-glycerol, oxo-arsenosugar-phosphate, oxo-arsenosugar-sulfonate, and oxo-arsenosugar-sulfate, was achieved by HPLC-ICP-MS with the column along with a mobile phase of 0.05% heptafluorobutyric acid–methanol (99:1, volume per volume).</description><identifier>ISSN: 0910-6340</identifier><identifier>EISSN: 1348-2246</identifier><identifier>DOI: 10.2116/analsci.20N019</identifier><identifier>PMID: 32921649</identifier><language>eng</language><publisher>Singapore: The Japan Society for Analytical Chemistry</publisher><subject>Acids ; Analytical Chemistry ; Arsenates ; Arsenic ; Arsenite ; arsenosugar ; Chemistry ; Dimethylarsinic acid ; fluorocarbon ; Glycerol ; High-performance liquid chromatography ; HPLC ; ICP-MS ; Ion pairs ; Liquid chromatography ; Parameter modification ; pentafluorophenyl ; perfluoroalkyl ; Perfluorocarbons ; Reagents ; Separation ; Speciation ; Species ; Stationary phase</subject><ispartof>Analytical Sciences, 2021/02/10, Vol.37(2), pp.381-386</ispartof><rights>2021 by The Japan Society for Analytical Chemistry</rights><rights>The Japan Society for Analytical Chemistry 2021</rights><rights>Copyright Japan Science and Technology Agency 2021</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c568t-7b1180e5a01ebb3c3736d6b007d4329c4f185f3b98b93a338474682552803c7f3</citedby><cites>FETCH-LOGICAL-c568t-7b1180e5a01ebb3c3736d6b007d4329c4f185f3b98b93a338474682552803c7f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.2116/analsci.20N019$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.2116/analsci.20N019$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,1877,27901,27902,41464,42533,51294</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/32921649$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>MIYASHITA, Shin-ichi</creatorcontrib><creatorcontrib>KINOSHITA, Kenji</creatorcontrib><creatorcontrib>KAISE, Toshikazu</creatorcontrib><title>A Simple and Effective Method for Speciation Analysis of 13 Arsenic Species Using HPLC on a Fluorocarbon Stationary Phase Coupled to ICP-MS</title><title>Analytical Sciences</title><addtitle>ANAL. SCI</addtitle><addtitle>Anal Sci</addtitle><description>The separation properties of arsenic species was investigated using HPLC-ICP-MS with several commercially available fluorocarbon stationary phases and no ion-pair reagents in HPLC. One pentafluorophenyl column showed the highest potential for the separation of a larger number of arsenic species when using simple acid-based mobile phases. After modification of the operational parameters in HPLC, the speciation analysis of 13 representative arsenic species: arsenite, arsenate, methylarsonic acid, dimethylarsinic acid, trimethylarsine oxide, tetramethylarsonium, arsenobetaine, arsenocholine, thio-dimethylarsinic acid, oxo-arsenosugar-glycerol, oxo-arsenosugar-phosphate, oxo-arsenosugar-sulfonate, and oxo-arsenosugar-sulfate, was achieved by HPLC-ICP-MS with the column along with a mobile phase of 0.05% heptafluorobutyric acid–methanol (99:1, volume per volume).</description><subject>Acids</subject><subject>Analytical Chemistry</subject><subject>Arsenates</subject><subject>Arsenic</subject><subject>Arsenite</subject><subject>arsenosugar</subject><subject>Chemistry</subject><subject>Dimethylarsinic acid</subject><subject>fluorocarbon</subject><subject>Glycerol</subject><subject>High-performance liquid chromatography</subject><subject>HPLC</subject><subject>ICP-MS</subject><subject>Ion pairs</subject><subject>Liquid chromatography</subject><subject>Parameter modification</subject><subject>pentafluorophenyl</subject><subject>perfluoroalkyl</subject><subject>Perfluorocarbons</subject><subject>Reagents</subject><subject>Separation</subject><subject>Speciation</subject><subject>Species</subject><subject>Stationary phase</subject><issn>0910-6340</issn><issn>1348-2246</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp1kUuL2zAUhUVp6aTTbrssgm66cUYv29IyuPOCTBtIZ21k-TpRcKxUkgvzG_qnRxOnKRS6kRD3u-dwdBD6SMmcUVpc6UH3wdg5I98IVa_QjHIhM8ZE8RrNiKIkK7ggF-hdCDtCKJOMvUUXnClGC6Fm6PcCr-3-0APWQ4uvuw5MtL8AP0DcuhZ3zuP1AYzV0boBL5LbU7ABuw5Tjhc-wGDNREDAj8EOG3y3WlY4wRrf9KPzzmjfpOc6HjW0f8KrrQ6AKzcm3xZHh--rVfawfo_edCkNfDjdl-jx5vpHdZctv9_eV4tlZvJCxqxsKJUEck0oNA03vORFWzSElK1IwYzoqMw73ijZKK45l6IUhWR5ziThpuz4Jfoy6R68-zlCiPXeBgN9rwdwY6iZECxXqlQkoZ__QXdu9C9_niiVE8ZkKRI1nyjjXQgeuvrg7T4lrSmpX2qqTzXVU01p4dNJdmz20J7xP70k4GoCQhoNG_B_ff8r-XXa2IWoN3CW1D5a08MZ52XNjsdx7Tw2W-1rGPgzcw-1ew</recordid><startdate>20210210</startdate><enddate>20210210</enddate><creator>MIYASHITA, Shin-ichi</creator><creator>KINOSHITA, Kenji</creator><creator>KAISE, Toshikazu</creator><general>The Japan Society for Analytical Chemistry</general><general>Springer Nature Singapore</general><general>Japan Science and Technology Agency</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SE</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>FR3</scope><scope>H8G</scope><scope>JG9</scope><scope>L7M</scope><scope>P64</scope><scope>7X8</scope></search><sort><creationdate>20210210</creationdate><title>A Simple and Effective Method for Speciation Analysis of 13 Arsenic Species Using HPLC on a Fluorocarbon Stationary Phase Coupled to ICP-MS</title><author>MIYASHITA, Shin-ichi ; 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After modification of the operational parameters in HPLC, the speciation analysis of 13 representative arsenic species: arsenite, arsenate, methylarsonic acid, dimethylarsinic acid, trimethylarsine oxide, tetramethylarsonium, arsenobetaine, arsenocholine, thio-dimethylarsinic acid, oxo-arsenosugar-glycerol, oxo-arsenosugar-phosphate, oxo-arsenosugar-sulfonate, and oxo-arsenosugar-sulfate, was achieved by HPLC-ICP-MS with the column along with a mobile phase of 0.05% heptafluorobutyric acid–methanol (99:1, volume per volume).</abstract><cop>Singapore</cop><pub>The Japan Society for Analytical Chemistry</pub><pmid>32921649</pmid><doi>10.2116/analsci.20N019</doi><tpages>6</tpages><oa>free_for_read</oa></addata></record> |
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| subjects | Acids Analytical Chemistry Arsenates Arsenic Arsenite arsenosugar Chemistry Dimethylarsinic acid fluorocarbon Glycerol High-performance liquid chromatography HPLC ICP-MS Ion pairs Liquid chromatography Parameter modification pentafluorophenyl perfluoroalkyl Perfluorocarbons Reagents Separation Speciation Species Stationary phase |
| title | A Simple and Effective Method for Speciation Analysis of 13 Arsenic Species Using HPLC on a Fluorocarbon Stationary Phase Coupled to ICP-MS |
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