Helicity Control of Polymeric Backbones with Alternating cis‐trans Double Bonds in Cyclopolymerized Dipropargyl Amides

We report the synthesis of new helical polymeric structures having alternating cis and trans double bonds and chiral amino acid side chains by metathesis cyclopolymerization. The polymer helicity, which is generated by the interaction between fluorenylmethyloxycarbonyl (Fmoc) groups in the side chai...

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Veröffentlicht in:	Angewandte Chemie International Edition 2020-12, Vol.59 (51), p.22968-22972
Hauptverfasser:	Song, Youngjun, Kang, Sunyoung, Kang, Sangyoon, Lee, Yan
Format:	Artikel
Sprache:	eng
Schlagworte:	Amides Amino acids Atomic force microscopy Chemical synthesis Density functional theory helical structures Helicity Metathesis metathesis polymer NMR Nuclear magnetic resonance Polymers solvent effect Solvents Theoretical analysis
Online-Zugang:	Volltext
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