Divergent Coupling of Benzocyclobutenones with Indoles via C−H and C−C Activations

Highly selective divergent coupling reactions of benzocyclobutenones and indoles, in which the chemoselectivity is controlled by catalysts, are reported herein. The substrates undergo C2(indole)–C8(benzocyclobutenone) coupling to produce benzylated indoles and benzo[b]carbazoles in the Ni‐ and Ru‐ca...

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Veröffentlicht in:	Angewandte Chemie International Edition 2020-12, Vol.59 (52), p.23537-23543
Hauptverfasser:	Lu, Hong, Zhao, Tian‐Tian, Bai, Jin‐Hua, Ye, Dan, Xu, Peng‐Fei, Wei, Hao
Format:	Artikel
Sprache:	eng
Schlagworte:	benzocyclobutenone carbazole Carbazoles catalyst-control Catalysts Chemical reactions Coupling C−C activation Divergence divergent synthesis Indoles Selectivity Substrates
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