Comment to the article “Hydroxyl radical scavenging by solid mineral surfaces in oxidative treatment systems: Rate constants and implications” published by K. Rusevova Crincoli and S. G. Huling in Water Research 169, 2020, 115240
The fate of radicals in aqueous suspensions can be significantly affected by surfaces scavenging reactions. When short-lived radicals such as •OH are considered, mass-transfer limitation may come into play. Disregarding these limitations may lead to heavy overestimation of surface-mediated reactions...
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| Veröffentlicht in: | Water research (Oxford) 2020-11, Vol.186, p.116308-116308, Article 116308 |
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| container_title | Water research (Oxford) |
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| creator | Kopinke, Frank-Dieter |
| description | The fate of radicals in aqueous suspensions can be significantly affected by surfaces scavenging reactions. When short-lived radicals such as •OH are considered, mass-transfer limitation may come into play. Disregarding these limitations may lead to heavy overestimation of surface-mediated reactions. The present comment exposes a potential misinterpretation of experimental data in a recent study with implications for in-situ chemical oxidation (ISCO) techniques.
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| doi_str_mv | 10.1016/j.watres.2020.116308 |
| format | Article |
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| identifier | ISSN: 0043-1354 |
| ispartof | Water research (Oxford), 2020-11, Vol.186, p.116308-116308, Article 116308 |
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| language | eng |
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| source | Access via ScienceDirect (Elsevier) |
| subjects | In-situ chemical oxidation Mass-transfer limitation Radical reactions Surface scavenging |
| title | Comment to the article “Hydroxyl radical scavenging by solid mineral surfaces in oxidative treatment systems: Rate constants and implications” published by K. Rusevova Crincoli and S. G. Huling in Water Research 169, 2020, 115240 |
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