High-Pressure Synthesis and Crystal Structure of the Sulfur-Richest Chromium Sulfide CrS3 Composed of Cr(III) and Disulfide Ions

High-Pressure Synthesis and Crystal Structure of the Sulfur-Richest Chromium Sulfide CrS3 Composed of Cr(III) and Disulfide Ions

The new binary chromium sulfide CrS3 has been synthesized by reaction of Cr3S4 and sulfur mixtures at 800 °C and 13 GPa. CrS3 crystallizes in an orthorhombic unit cell with a = 4.6742(7) Å, b = 5.7315(8) Å, c = 10.603(2) Å, and V = 284.873(4) Å3. It has a novel structure composed of Cr2S10 edge-shar...

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Veröffentlicht in:Inorganic chemistry 2020-09, Vol.59 (18), p.13320-13325
Hauptverfasser: Fukuoka, Hiroshi, Kawata, Naomi, Furuta, Masahiro, Katakami, Yuta, Kimura, Sota, Inumaru, Kei
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container_end_page 13325
container_issue 18
container_start_page 13320
container_title Inorganic chemistry
container_volume 59
creator Fukuoka, Hiroshi
Kawata, Naomi
Furuta, Masahiro
Katakami, Yuta
Kimura, Sota
Inumaru, Kei
description The new binary chromium sulfide CrS3 has been synthesized by reaction of Cr3S4 and sulfur mixtures at 800 °C and 13 GPa. CrS3 crystallizes in an orthorhombic unit cell with a = 4.6742(7) Å, b = 5.7315(8) Å, c = 10.603(2) Å, and V = 284.873(4) Å3. It has a novel structure composed of Cr2S10 edge-shared octahedral dimers, which share all of their corners to form a three-dimensional structure. All of the sulfur atoms form S2 2– disulfide ions with a S–S distance of 2.063(5) or 2.068(8) Å. The structure of CrS3 is a derivative of the crystal structure of marcasite FeS2, in which one in three metal sites of the marcasite structure is vacant in the CrS3 structure.
doi_str_mv 10.1021/acs.inorgchem.0c01690
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title High-Pressure Synthesis and Crystal Structure of the Sulfur-Richest Chromium Sulfide CrS3 Composed of Cr(III) and Disulfide Ions
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