In-situ fabrication of zeolite imidazole framework@hydroxyapatite composite for dispersive solid-phase extraction of benzodiazepines and their determination with high-performance liquid chromatography-VWD detection
A novel zeolite imidazole framework@hydroxyapatite composite (ZIF-8@HAP) was constructed via in-situ growth and developed for efficient dispersive solid-phase extraction (DSPE) of three benzodiazepines from urine samples. The prepared composite was characterized by scanning electron microscopy, ener...
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| Veröffentlicht in: | Mikrochimica acta (1966) 2020-09, Vol.187 (9), p.540-540, Article 540 |
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| container_title | Mikrochimica acta (1966) |
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| creator | Li, Zi-Ling Zhang, Zi-Yang Zhao, Teng-Wen Meng, Chun-Yan Zhang, Qian-Ying Wang, Man-Man |
| description | A novel zeolite imidazole framework@hydroxyapatite composite (ZIF-8@HAP) was constructed via in-situ growth and developed for efficient dispersive solid-phase extraction (DSPE) of three benzodiazepines from urine samples. The prepared composite was characterized by scanning electron microscopy, energy-dispersive spectrometer, Fourier-transform infrared spectrometry, X-ray diffractometry, zeta potential analyzer, and nitrogen adsorption-desorption experiment. Characterization results showed typical dodecahedron ZIF-8 crystals that were uniformly located on the surface of rod-like HAP. The combination of ZIF-8 and HAP made the surface area significantly enhanced from 4.68 to 205.44 m
2
g
−1
. Compared with a commercial C
18
adsorbent, ZIF-8@HAP exhibited superior removal performance for interfering components from urine and offered better extraction properties for the analytes. The prepared ZIF-8@HAP was applied as an adsorbent in DSPE, and the main experimental parameters, including pH and ionic strength of solution, adsorbent amount, adsorption time, elution solvent, and volume, were investigated. Under optimal conditions, the adsorption for 250 ng mL
−1
of each analyte in 4 mL of urine was accomplished within 2 min using 60 mg of adsorbent. The method of ZIF-8@HAP–based DSPE followed by high-performance liquid chromatography gave enhancement factors of 13.3–15.3, linear ranges of 2.5–500 ng mL
−1
, and limits of detection (
S/N
= 3) of 0.7–1.4 ng mL
−1
. The relative recoveries at three spiked levels ranged from 88.7 - 102% with intra-day and inter-day precisions from 3.0 - 10.3% and 2.3 - 12.3%, respectively. These results indicated that the proposed strategy had promising applicability for convenient, rapid, and efficient determination of benzodiazepines in urine samples.
Graphical abstract
In-situ fabrication of ZIF-8@HAP composite for dispersive solid-phase extraction of benzodiazepines in urine samples. |
| doi_str_mv | 10.1007/s00604-020-04517-y |
| format | Article |
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2
g
−1
. Compared with a commercial C
18
adsorbent, ZIF-8@HAP exhibited superior removal performance for interfering components from urine and offered better extraction properties for the analytes. The prepared ZIF-8@HAP was applied as an adsorbent in DSPE, and the main experimental parameters, including pH and ionic strength of solution, adsorbent amount, adsorption time, elution solvent, and volume, were investigated. Under optimal conditions, the adsorption for 250 ng mL
−1
of each analyte in 4 mL of urine was accomplished within 2 min using 60 mg of adsorbent. The method of ZIF-8@HAP–based DSPE followed by high-performance liquid chromatography gave enhancement factors of 13.3–15.3, linear ranges of 2.5–500 ng mL
−1
, and limits of detection (
S/N
= 3) of 0.7–1.4 ng mL
−1
. The relative recoveries at three spiked levels ranged from 88.7 - 102% with intra-day and inter-day precisions from 3.0 - 10.3% and 2.3 - 12.3%, respectively. These results indicated that the proposed strategy had promising applicability for convenient, rapid, and efficient determination of benzodiazepines in urine samples.
Graphical abstract
In-situ fabrication of ZIF-8@HAP composite for dispersive solid-phase extraction of benzodiazepines in urine samples.</description><identifier>ISSN: 0026-3672</identifier><identifier>EISSN: 1436-5073</identifier><identifier>DOI: 10.1007/s00604-020-04517-y</identifier><language>eng</language><publisher>Vienna: Springer Vienna</publisher><subject>Adsorbents ; Adsorption ; Analytical Chemistry ; Antianxiety agents ; Antifungal agents ; Benzodiazepines ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Chromatography ; Comparative analysis ; Dispersion ; Elution ; Fourier transforms ; High performance liquid chromatography ; Hydroxyapatite ; Imidazole ; Infrared analysis ; Infrared spectrometers ; Infrared spectroscopy ; Microengineering ; Nanochemistry ; Nanotechnology ; Nitrogen ; Original Paper ; Solid phases ; Surface chemistry ; Urine ; Zeolites ; Zeta potential</subject><ispartof>Mikrochimica acta (1966), 2020-09, Vol.187 (9), p.540-540, Article 540</ispartof><rights>Springer-Verlag GmbH Austria, part of Springer Nature 2020</rights><rights>COPYRIGHT 2020 Springer</rights><rights>Springer-Verlag GmbH Austria, part of Springer Nature 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c419t-eae48593cdbfd14941caff2ad66e19b8082294e0528f0994378bbf7daf14b8ab3</citedby><cites>FETCH-LOGICAL-c419t-eae48593cdbfd14941caff2ad66e19b8082294e0528f0994378bbf7daf14b8ab3</cites><orcidid>0000-0002-1801-6321</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00604-020-04517-y$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00604-020-04517-y$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,777,781,27905,27906,41469,42538,51300</link.rule.ids></links><search><creatorcontrib>Li, Zi-Ling</creatorcontrib><creatorcontrib>Zhang, Zi-Yang</creatorcontrib><creatorcontrib>Zhao, Teng-Wen</creatorcontrib><creatorcontrib>Meng, Chun-Yan</creatorcontrib><creatorcontrib>Zhang, Qian-Ying</creatorcontrib><creatorcontrib>Wang, Man-Man</creatorcontrib><title>In-situ fabrication of zeolite imidazole framework@hydroxyapatite composite for dispersive solid-phase extraction of benzodiazepines and their determination with high-performance liquid chromatography-VWD detection</title><title>Mikrochimica acta (1966)</title><addtitle>Microchim Acta</addtitle><description>A novel zeolite imidazole framework@hydroxyapatite composite (ZIF-8@HAP) was constructed via in-situ growth and developed for efficient dispersive solid-phase extraction (DSPE) of three benzodiazepines from urine samples. The prepared composite was characterized by scanning electron microscopy, energy-dispersive spectrometer, Fourier-transform infrared spectrometry, X-ray diffractometry, zeta potential analyzer, and nitrogen adsorption-desorption experiment. Characterization results showed typical dodecahedron ZIF-8 crystals that were uniformly located on the surface of rod-like HAP. The combination of ZIF-8 and HAP made the surface area significantly enhanced from 4.68 to 205.44 m
2
g
−1
. Compared with a commercial C
18
adsorbent, ZIF-8@HAP exhibited superior removal performance for interfering components from urine and offered better extraction properties for the analytes. The prepared ZIF-8@HAP was applied as an adsorbent in DSPE, and the main experimental parameters, including pH and ionic strength of solution, adsorbent amount, adsorption time, elution solvent, and volume, were investigated. Under optimal conditions, the adsorption for 250 ng mL
−1
of each analyte in 4 mL of urine was accomplished within 2 min using 60 mg of adsorbent. The method of ZIF-8@HAP–based DSPE followed by high-performance liquid chromatography gave enhancement factors of 13.3–15.3, linear ranges of 2.5–500 ng mL
−1
, and limits of detection (
S/N
= 3) of 0.7–1.4 ng mL
−1
. The relative recoveries at three spiked levels ranged from 88.7 - 102% with intra-day and inter-day precisions from 3.0 - 10.3% and 2.3 - 12.3%, respectively. These results indicated that the proposed strategy had promising applicability for convenient, rapid, and efficient determination of benzodiazepines in urine samples.
Graphical abstract
In-situ fabrication of ZIF-8@HAP composite for dispersive solid-phase extraction of benzodiazepines in urine samples.</description><subject>Adsorbents</subject><subject>Adsorption</subject><subject>Analytical Chemistry</subject><subject>Antianxiety agents</subject><subject>Antifungal agents</subject><subject>Benzodiazepines</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chromatography</subject><subject>Comparative analysis</subject><subject>Dispersion</subject><subject>Elution</subject><subject>Fourier transforms</subject><subject>High performance liquid chromatography</subject><subject>Hydroxyapatite</subject><subject>Imidazole</subject><subject>Infrared analysis</subject><subject>Infrared spectrometers</subject><subject>Infrared spectroscopy</subject><subject>Microengineering</subject><subject>Nanochemistry</subject><subject>Nanotechnology</subject><subject>Nitrogen</subject><subject>Original Paper</subject><subject>Solid phases</subject><subject>Surface chemistry</subject><subject>Urine</subject><subject>Zeolites</subject><subject>Zeta potential</subject><issn>0026-3672</issn><issn>1436-5073</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9kktvFSEYhidGE4_VP-CKxI0bKjDMbWdTb02auPGyJAx8nKHOwBRm2s75of4emTM1jcYYFhDyPC9fyJtlLyk5pYRUbyIhJeGYMIIJL2iFl0fZjvK8xAWp8sfZjhBW4rys2NPsWYxXhNCqZHyX_bxwONppRka2wSo5We-QN-gAvrcTIDtYLQ--B2SCHODWhx9vu0UHf7fIMdEJUX4YfVxPxgekbRwhRHsDKKYIjcdORkBwNwWpfqe34A5eW3mA0TqISDqNpg5s0mGCMFi3DXJrpw51dt_hlJnSB-kUoN5ez1Yj1QU_yMnvgxy7BX_7_u5oHx95nj0xso_w4n4_yb5-eP_l_BO-_Pzx4vzsEitOmwmDBF4XTa50azTlDadKGsOkLkugTVuTmrGGAylYbUjT8Lyq29ZUWhrK21q2-Un2essdg7-eIU5isFFB30sHfo6C8bwpc1bVPKGv_kKv_Bxcmu6eKhvKHqi97EFYZ_z6b2uoOKtoQYqy4it1-g8qLQ2DVd6Bsen-D4Ftggo-xgBGjMEOMiyCErE2SGwNEqlB4tggsSQp36SYYLeH8DDxf6xf0_bQNQ</recordid><startdate>20200901</startdate><enddate>20200901</enddate><creator>Li, Zi-Ling</creator><creator>Zhang, Zi-Yang</creator><creator>Zhao, Teng-Wen</creator><creator>Meng, Chun-Yan</creator><creator>Zhang, Qian-Ying</creator><creator>Wang, Man-Man</creator><general>Springer Vienna</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>K9.</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-1801-6321</orcidid></search><sort><creationdate>20200901</creationdate><title>In-situ fabrication of zeolite imidazole framework@hydroxyapatite composite for dispersive solid-phase extraction of benzodiazepines and their determination with high-performance liquid chromatography-VWD detection</title><author>Li, Zi-Ling ; Zhang, Zi-Yang ; Zhao, Teng-Wen ; Meng, Chun-Yan ; Zhang, Qian-Ying ; Wang, Man-Man</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c419t-eae48593cdbfd14941caff2ad66e19b8082294e0528f0994378bbf7daf14b8ab3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Adsorbents</topic><topic>Adsorption</topic><topic>Analytical Chemistry</topic><topic>Antianxiety agents</topic><topic>Antifungal agents</topic><topic>Benzodiazepines</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chromatography</topic><topic>Comparative analysis</topic><topic>Dispersion</topic><topic>Elution</topic><topic>Fourier transforms</topic><topic>High performance liquid chromatography</topic><topic>Hydroxyapatite</topic><topic>Imidazole</topic><topic>Infrared analysis</topic><topic>Infrared spectrometers</topic><topic>Infrared spectroscopy</topic><topic>Microengineering</topic><topic>Nanochemistry</topic><topic>Nanotechnology</topic><topic>Nitrogen</topic><topic>Original Paper</topic><topic>Solid phases</topic><topic>Surface chemistry</topic><topic>Urine</topic><topic>Zeolites</topic><topic>Zeta potential</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Zi-Ling</creatorcontrib><creatorcontrib>Zhang, Zi-Yang</creatorcontrib><creatorcontrib>Zhao, Teng-Wen</creatorcontrib><creatorcontrib>Meng, Chun-Yan</creatorcontrib><creatorcontrib>Zhang, Qian-Ying</creatorcontrib><creatorcontrib>Wang, Man-Man</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Mikrochimica acta (1966)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Zi-Ling</au><au>Zhang, Zi-Yang</au><au>Zhao, Teng-Wen</au><au>Meng, Chun-Yan</au><au>Zhang, Qian-Ying</au><au>Wang, Man-Man</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>In-situ fabrication of zeolite imidazole framework@hydroxyapatite composite for dispersive solid-phase extraction of benzodiazepines and their determination with high-performance liquid chromatography-VWD detection</atitle><jtitle>Mikrochimica acta (1966)</jtitle><stitle>Microchim Acta</stitle><date>2020-09-01</date><risdate>2020</risdate><volume>187</volume><issue>9</issue><spage>540</spage><epage>540</epage><pages>540-540</pages><artnum>540</artnum><issn>0026-3672</issn><eissn>1436-5073</eissn><abstract>A novel zeolite imidazole framework@hydroxyapatite composite (ZIF-8@HAP) was constructed via in-situ growth and developed for efficient dispersive solid-phase extraction (DSPE) of three benzodiazepines from urine samples. The prepared composite was characterized by scanning electron microscopy, energy-dispersive spectrometer, Fourier-transform infrared spectrometry, X-ray diffractometry, zeta potential analyzer, and nitrogen adsorption-desorption experiment. Characterization results showed typical dodecahedron ZIF-8 crystals that were uniformly located on the surface of rod-like HAP. The combination of ZIF-8 and HAP made the surface area significantly enhanced from 4.68 to 205.44 m
2
g
−1
. Compared with a commercial C
18
adsorbent, ZIF-8@HAP exhibited superior removal performance for interfering components from urine and offered better extraction properties for the analytes. The prepared ZIF-8@HAP was applied as an adsorbent in DSPE, and the main experimental parameters, including pH and ionic strength of solution, adsorbent amount, adsorption time, elution solvent, and volume, were investigated. Under optimal conditions, the adsorption for 250 ng mL
−1
of each analyte in 4 mL of urine was accomplished within 2 min using 60 mg of adsorbent. The method of ZIF-8@HAP–based DSPE followed by high-performance liquid chromatography gave enhancement factors of 13.3–15.3, linear ranges of 2.5–500 ng mL
−1
, and limits of detection (
S/N
= 3) of 0.7–1.4 ng mL
−1
. The relative recoveries at three spiked levels ranged from 88.7 - 102% with intra-day and inter-day precisions from 3.0 - 10.3% and 2.3 - 12.3%, respectively. These results indicated that the proposed strategy had promising applicability for convenient, rapid, and efficient determination of benzodiazepines in urine samples.
Graphical abstract
In-situ fabrication of ZIF-8@HAP composite for dispersive solid-phase extraction of benzodiazepines in urine samples.</abstract><cop>Vienna</cop><pub>Springer Vienna</pub><doi>10.1007/s00604-020-04517-y</doi><tpages>1</tpages><orcidid>https://orcid.org/0000-0002-1801-6321</orcidid></addata></record> |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Adsorbents Adsorption Analytical Chemistry Antianxiety agents Antifungal agents Benzodiazepines Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Chromatography Comparative analysis Dispersion Elution Fourier transforms High performance liquid chromatography Hydroxyapatite Imidazole Infrared analysis Infrared spectrometers Infrared spectroscopy Microengineering Nanochemistry Nanotechnology Nitrogen Original Paper Solid phases Surface chemistry Urine Zeolites Zeta potential |
| title | In-situ fabrication of zeolite imidazole framework@hydroxyapatite composite for dispersive solid-phase extraction of benzodiazepines and their determination with high-performance liquid chromatography-VWD detection |
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