Asymmetric Transformation Driven by Confinement and Self‐Release in Single‐Layered Porous Nanosheets

Reported here is the use of single‐layered, chiral porous sheets with induced pore chirality for repeatable asymmetric transformations and self‐separation without the need for chiral catalysts or chiral auxiliaries. The asymmetric induction is driven by chiral fixation of absorbed achiral substrates...

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Veröffentlicht in:	Angewandte Chemie International Edition 2020-12, Vol.59 (50), p.22690-22696
Hauptverfasser:	Sun, Bo, Shen, Bowen, Urushima, Akio, Liu, Xin, Feng, Xiaopeng, Yashima, Eiji, Lee, Myongsoo
Format:	Artikel
Sprache:	eng
Schlagworte:	Asymmetric synthesis Asymmetry Catalysts Chirality Confinement macrocycles materials chemistry Nanosheets Pores Porous materials Sheets Substrates Transformations
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