Molten Salt Synthesis of an Open-Frame Aluminum Phosphate Ba3Al2P4O16 with a Rare-Pyramidal AlO5 Group

Molten Salt Synthesis of an Open-Frame Aluminum Phosphate Ba3Al2P4O16 with a Rare-Pyramidal AlO5 Group

A new open-frame aluminophosphate, Ba3Al2P4O16, was synthesized by a high-temperature flux method. Ba3Al2P4O16 features discrete [Al4P8O32]∞ 12– chains with rare square-pyramidal AlO5 groups adopted. Especially, this pyramidal AlO5 group acts as an ideal “plane builder” or “vacancy inducer” to const...

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Veröffentlicht in:Inorganic chemistry 2020-09, Vol.59 (18), p.12978-12982
Hauptverfasser: Duan, Meihong, Kong, Bo, Li, Rukang
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container_title Inorganic chemistry
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creator Duan, Meihong
Kong, Bo
Li, Rukang
description A new open-frame aluminophosphate, Ba3Al2P4O16, was synthesized by a high-temperature flux method. Ba3Al2P4O16 features discrete [Al4P8O32]∞ 12– chains with rare square-pyramidal AlO5 groups adopted. Especially, this pyramidal AlO5 group acts as an ideal “plane builder” or “vacancy inducer” to construct open-frame structures compared with an ordinary trigonal-bipyramidal AlO5 group.
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title Molten Salt Synthesis of an Open-Frame Aluminum Phosphate Ba3Al2P4O16 with a Rare-Pyramidal AlO5 Group
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