Unsaturated Alcohols as Chain-Transfer Agents in Olefin Polymerization: Synthesis of Aldehyde End-Capped Oligomers and Polymers

Palladium diimine-catalyzed polymerization of olefins using unsaturated alcohols as chain-transfer agents has been demonstrated. The reaction affords aldehyde end-capped polymers whose molecular weight can be tuned by varying the ratio of olefin/chain-transfer agent. Notably, >95% efficient end c...

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Veröffentlicht in:	Journal of the American Chemical Society 2020-09, Vol.142 (36), p.15431-15437
Hauptverfasser:	Han, Xing-Wang, Daugulis, Olafs, Brookhart, Maurice
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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