Impact of diffusion methods and metal cations on photochromic three-component D-A hybrid heterostructures
D-A hybrid heterostructures are an attractive class of hybrid complexes composed of semiconducting organic and inorganic components, which make them potential candidates for applications in the photoelectric fields, particularly as photochromic materials. Herein, we report that the combination of me...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2020-09, Vol.49 (35), p.12411-12417 |
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| creator | You, Ming-Hua Li, Meng-Hua Liu, Jing-Yan Lin, Mei-Jin |
| description | D-A hybrid heterostructures are an attractive class of hybrid complexes composed of semiconducting organic and inorganic components, which make them potential candidates for applications in the photoelectric fields, particularly as photochromic materials. Herein, we report that the combination of metal cations (M = Zn
2+
or Cd
2+
), silicomolybdic anions, and
N
,
N
-di(4-pyridyl)-1,4,5,8-naphthalene diimide (DPNDI)
via
two diffusion methods (A and B) led to four three-component D-A hybrid heterostructures with silicomolybdic anions as electron donors, and one-dimensional (1-D) naphthalenediimide coordination networks of different metal cations, [Zn
2
(DPNDI)
2
(H
2
O)
4
]·(SiMo
12
O
40
) (
1-A
and
1-B
) and [Cd
2
(DPNDI)
2
(H
2
O)
4
]·(SiMo
12
O
40
) (
2-A
and
2-B
), as electron acceptors. Although the different diffusion methods,
1-B
,
2-A
and
2-B
, are isostructures with close cell parameters. Due to the different ionic radii and electronegativity of metal cations in isostructural
1-B
and
2-B
, they exhibit different electron-transfer photochromic behaviors. This study paves a new path for designing novel photochromic materials through such third-component metal cations.
Four three-component D-A hybrid heterostructures have been obtained and the impacts of metal cations contained and diffusion methods used on their structures as well as photochromic properties have been discussed. |
| doi_str_mv | 10.1039/d0dt02532a |
| format | Article |
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2+
or Cd
2+
), silicomolybdic anions, and
N
,
N
-di(4-pyridyl)-1,4,5,8-naphthalene diimide (DPNDI)
via
two diffusion methods (A and B) led to four three-component D-A hybrid heterostructures with silicomolybdic anions as electron donors, and one-dimensional (1-D) naphthalenediimide coordination networks of different metal cations, [Zn
2
(DPNDI)
2
(H
2
O)
4
]·(SiMo
12
O
40
) (
1-A
and
1-B
) and [Cd
2
(DPNDI)
2
(H
2
O)
4
]·(SiMo
12
O
40
) (
2-A
and
2-B
), as electron acceptors. Although the different diffusion methods,
1-B
,
2-A
and
2-B
, are isostructures with close cell parameters. Due to the different ionic radii and electronegativity of metal cations in isostructural
1-B
and
2-B
, they exhibit different electron-transfer photochromic behaviors. This study paves a new path for designing novel photochromic materials through such third-component metal cations.
Four three-component D-A hybrid heterostructures have been obtained and the impacts of metal cations contained and diffusion methods used on their structures as well as photochromic properties have been discussed.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/d0dt02532a</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Anions ; Cations ; Crystallography ; Diffusion ; Diimide ; Donors (electronic) ; Electronegativity ; Electrons ; Heterostructures ; Ions ; Metal ions ; Naphthalene ; Photochromism ; Photoelectricity</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2020-09, Vol.49 (35), p.12411-12417</ispartof><rights>Copyright Royal Society of Chemistry 2020</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c340t-ca9bec3e70116e56648bc6c4e931d7c67686eb89ad786704e13042eedeced26f3</citedby><cites>FETCH-LOGICAL-c340t-ca9bec3e70116e56648bc6c4e931d7c67686eb89ad786704e13042eedeced26f3</cites><orcidid>0000-0003-2008-9674</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>You, Ming-Hua</creatorcontrib><creatorcontrib>Li, Meng-Hua</creatorcontrib><creatorcontrib>Liu, Jing-Yan</creatorcontrib><creatorcontrib>Lin, Mei-Jin</creatorcontrib><title>Impact of diffusion methods and metal cations on photochromic three-component D-A hybrid heterostructures</title><title>Dalton transactions : an international journal of inorganic chemistry</title><description>D-A hybrid heterostructures are an attractive class of hybrid complexes composed of semiconducting organic and inorganic components, which make them potential candidates for applications in the photoelectric fields, particularly as photochromic materials. Herein, we report that the combination of metal cations (M = Zn
2+
or Cd
2+
), silicomolybdic anions, and
N
,
N
-di(4-pyridyl)-1,4,5,8-naphthalene diimide (DPNDI)
via
two diffusion methods (A and B) led to four three-component D-A hybrid heterostructures with silicomolybdic anions as electron donors, and one-dimensional (1-D) naphthalenediimide coordination networks of different metal cations, [Zn
2
(DPNDI)
2
(H
2
O)
4
]·(SiMo
12
O
40
) (
1-A
and
1-B
) and [Cd
2
(DPNDI)
2
(H
2
O)
4
]·(SiMo
12
O
40
) (
2-A
and
2-B
), as electron acceptors. Although the different diffusion methods,
1-B
,
2-A
and
2-B
, are isostructures with close cell parameters. Due to the different ionic radii and electronegativity of metal cations in isostructural
1-B
and
2-B
, they exhibit different electron-transfer photochromic behaviors. This study paves a new path for designing novel photochromic materials through such third-component metal cations.
Four three-component D-A hybrid heterostructures have been obtained and the impacts of metal cations contained and diffusion methods used on their structures as well as photochromic properties have been discussed.</description><subject>Anions</subject><subject>Cations</subject><subject>Crystallography</subject><subject>Diffusion</subject><subject>Diimide</subject><subject>Donors (electronic)</subject><subject>Electronegativity</subject><subject>Electrons</subject><subject>Heterostructures</subject><subject>Ions</subject><subject>Metal ions</subject><subject>Naphthalene</subject><subject>Photochromism</subject><subject>Photoelectricity</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9kU1Lw0AQhhdRsFYv3oUVLyJE9yub5FhaPwoFL_UcNrsTktJk4-7m0H_v1koFD55m4HkYZt5B6JqSR0p48WSICYSlnKkTNKEiy5KCcXF67Jk8RxfebwhhjKRsgtplNygdsK2xaet69K3tcQehscZj1Zt9r7ZYqxCBxxEOjQ1WN852rcahcQCJtt1ge-gDXiQz3Owq1xrcQABnfXCjDqMDf4nOarX1cPVTp-jj5Xk9f0tW76_L-WyVaC5ISLQqKtAcMkKphFRKkVdaagEFpybTMpO5hCovlMlymREBlBPBAAxoMEzWfIruD3MHZz9H8KHsWq9hu1U92NGXTPAsF4wTEtW7P-rGjq6P20VLsILKlMpoPRwsHc_xDupycG2n3K6kpNynXi7IYv2d-izKNwfZeX30fr8S-e1_vBxMzb8AcQmLIw</recordid><startdate>20200915</startdate><enddate>20200915</enddate><creator>You, Ming-Hua</creator><creator>Li, Meng-Hua</creator><creator>Liu, Jing-Yan</creator><creator>Lin, Mei-Jin</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-2008-9674</orcidid></search><sort><creationdate>20200915</creationdate><title>Impact of diffusion methods and metal cations on photochromic three-component D-A hybrid heterostructures</title><author>You, Ming-Hua ; Li, Meng-Hua ; Liu, Jing-Yan ; Lin, Mei-Jin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c340t-ca9bec3e70116e56648bc6c4e931d7c67686eb89ad786704e13042eedeced26f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Anions</topic><topic>Cations</topic><topic>Crystallography</topic><topic>Diffusion</topic><topic>Diimide</topic><topic>Donors (electronic)</topic><topic>Electronegativity</topic><topic>Electrons</topic><topic>Heterostructures</topic><topic>Ions</topic><topic>Metal ions</topic><topic>Naphthalene</topic><topic>Photochromism</topic><topic>Photoelectricity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>You, Ming-Hua</creatorcontrib><creatorcontrib>Li, Meng-Hua</creatorcontrib><creatorcontrib>Liu, Jing-Yan</creatorcontrib><creatorcontrib>Lin, Mei-Jin</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>You, Ming-Hua</au><au>Li, Meng-Hua</au><au>Liu, Jing-Yan</au><au>Lin, Mei-Jin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Impact of diffusion methods and metal cations on photochromic three-component D-A hybrid heterostructures</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><date>2020-09-15</date><risdate>2020</risdate><volume>49</volume><issue>35</issue><spage>12411</spage><epage>12417</epage><pages>12411-12417</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>D-A hybrid heterostructures are an attractive class of hybrid complexes composed of semiconducting organic and inorganic components, which make them potential candidates for applications in the photoelectric fields, particularly as photochromic materials. Herein, we report that the combination of metal cations (M = Zn
2+
or Cd
2+
), silicomolybdic anions, and
N
,
N
-di(4-pyridyl)-1,4,5,8-naphthalene diimide (DPNDI)
via
two diffusion methods (A and B) led to four three-component D-A hybrid heterostructures with silicomolybdic anions as electron donors, and one-dimensional (1-D) naphthalenediimide coordination networks of different metal cations, [Zn
2
(DPNDI)
2
(H
2
O)
4
]·(SiMo
12
O
40
) (
1-A
and
1-B
) and [Cd
2
(DPNDI)
2
(H
2
O)
4
]·(SiMo
12
O
40
) (
2-A
and
2-B
), as electron acceptors. Although the different diffusion methods,
1-B
,
2-A
and
2-B
, are isostructures with close cell parameters. Due to the different ionic radii and electronegativity of metal cations in isostructural
1-B
and
2-B
, they exhibit different electron-transfer photochromic behaviors. This study paves a new path for designing novel photochromic materials through such third-component metal cations.
Four three-component D-A hybrid heterostructures have been obtained and the impacts of metal cations contained and diffusion methods used on their structures as well as photochromic properties have been discussed.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d0dt02532a</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0003-2008-9674</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2020-09, Vol.49 (35), p.12411-12417 |
| issn | 1477-9226 1477-9234 |
| language | eng |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Anions Cations Crystallography Diffusion Diimide Donors (electronic) Electronegativity Electrons Heterostructures Ions Metal ions Naphthalene Photochromism Photoelectricity |
| title | Impact of diffusion methods and metal cations on photochromic three-component D-A hybrid heterostructures |
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