Rapid and Efficient Removal of Perfluorooctanoic Acid from Water with Fluorine-Rich Calixarene-Based Porous Polymers
On account of its nonbiodegradable nature and persistence in the environment, perfluorooctanoic acid (PFOA) accumulates in water resources and poses serious environmental issues in many parts of the world. Here, we present the development of two fluorine-rich calix[4]arene-based porous polymers, FC...
Gespeichert in:
| Veröffentlicht in: | ACS applied materials & interfaces 2020-09, Vol.12 (38), p.43160-43166 |
|---|---|
| Hauptverfasser: | , , , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 43166 |
|---|---|
| container_issue | 38 |
| container_start_page | 43160 |
| container_title | ACS applied materials & interfaces |
| container_volume | 12 |
| creator | Shetty, Dinesh Jahović, Ilma Skorjanc, Tina Erkal, Turan Selman Ali, Liaqat Raya, Jesus Asfari, Zouhair Olson, Mark A Kirmizialtin, Serdal Yazaydin, A. Ozgur Trabolsi, Ali |
| description | On account of its nonbiodegradable nature and persistence in the environment, perfluorooctanoic acid (PFOA) accumulates in water resources and poses serious environmental issues in many parts of the world. Here, we present the development of two fluorine-rich calix[4]arene-based porous polymers, FCX4-P and FCX4-BP, and demonstrate their utility for the efficient removal of PFOA from water. These materials featured Brunauer–Emmett–Teller (BET) surface areas of up to 450 m2 g–1, which is slightly lower than their nonfluorinated counterparts (up to 596 m2 g–1). FCX4-P removes PFOA at environmentally relevant concentrations with a high rate constant of 3.80 g mg–1 h–1 and reached an exceptional maximum PFOA uptake capacity of 188.7 mg g–1. In addition, it could be regenerated by simple methanol wash and reused without a significant decrease in performance. |
| doi_str_mv | 10.1021/acsami.0c13400 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_2437841468</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2437841468</sourcerecordid><originalsourceid>FETCH-LOGICAL-a347t-6ac4b060a7bee874504257f3adca79633a2db1f901fd062883f0ab2537b28f633</originalsourceid><addsrcrecordid>eNp1kMtLAzEQxoMoWKtXzzmKsDWvffRYS6tCwVIUj2E2m9CU3U1NdtX-96Zs8eZpXr_5mPkQuqVkQgmjD6ACNHZCFOWCkDM0olMhkoKl7PwvF-ISXYWwIyTjjKQj1G1gbysMbYUXxlhlddvhjW7cF9TYGbzW3tS9886pDlpnFZ6pyBvvGvwBnfb423ZbvDwyttXJxqotnkNtf8DrWD9C0BVeR4E-xFAfGu3DNbowUAd9c4pj9L5cvM2fk9Xr08t8tkqAi7xLMlCiJBmBvNS6yEVKBEtzw6FSkE8zzoFVJTVTQk1FMlYU3BAoWcrzkhUmzsfobtDde_fZ69DJxgal6xpaHe-RTPC8EFRkRUQnA6q8C8FrI_feNuAPkhJ5tFcO9sqTvXHhfliIfblzvW_jJ__Bv1y8fb0</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2437841468</pqid></control><display><type>article</type><title>Rapid and Efficient Removal of Perfluorooctanoic Acid from Water with Fluorine-Rich Calixarene-Based Porous Polymers</title><source>ACS Publications</source><creator>Shetty, Dinesh ; Jahović, Ilma ; Skorjanc, Tina ; Erkal, Turan Selman ; Ali, Liaqat ; Raya, Jesus ; Asfari, Zouhair ; Olson, Mark A ; Kirmizialtin, Serdal ; Yazaydin, A. Ozgur ; Trabolsi, Ali</creator><creatorcontrib>Shetty, Dinesh ; Jahović, Ilma ; Skorjanc, Tina ; Erkal, Turan Selman ; Ali, Liaqat ; Raya, Jesus ; Asfari, Zouhair ; Olson, Mark A ; Kirmizialtin, Serdal ; Yazaydin, A. Ozgur ; Trabolsi, Ali</creatorcontrib><description>On account of its nonbiodegradable nature and persistence in the environment, perfluorooctanoic acid (PFOA) accumulates in water resources and poses serious environmental issues in many parts of the world. Here, we present the development of two fluorine-rich calix[4]arene-based porous polymers, FCX4-P and FCX4-BP, and demonstrate their utility for the efficient removal of PFOA from water. These materials featured Brunauer–Emmett–Teller (BET) surface areas of up to 450 m2 g–1, which is slightly lower than their nonfluorinated counterparts (up to 596 m2 g–1). FCX4-P removes PFOA at environmentally relevant concentrations with a high rate constant of 3.80 g mg–1 h–1 and reached an exceptional maximum PFOA uptake capacity of 188.7 mg g–1. In addition, it could be regenerated by simple methanol wash and reused without a significant decrease in performance.</description><identifier>ISSN: 1944-8244</identifier><identifier>EISSN: 1944-8252</identifier><identifier>DOI: 10.1021/acsami.0c13400</identifier><language>eng</language><publisher>American Chemical Society</publisher><subject>Applications of Polymer, Composite, and Coating Materials</subject><ispartof>ACS applied materials & interfaces, 2020-09, Vol.12 (38), p.43160-43166</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a347t-6ac4b060a7bee874504257f3adca79633a2db1f901fd062883f0ab2537b28f633</citedby><cites>FETCH-LOGICAL-a347t-6ac4b060a7bee874504257f3adca79633a2db1f901fd062883f0ab2537b28f633</cites><orcidid>0000-0001-7494-7887 ; 0000-0001-8380-5725 ; 0000-0003-0398-5063 ; 0000-0001-8562-723X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/acsami.0c13400$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/acsami.0c13400$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2765,27076,27924,27925,56738,56788</link.rule.ids></links><search><creatorcontrib>Shetty, Dinesh</creatorcontrib><creatorcontrib>Jahović, Ilma</creatorcontrib><creatorcontrib>Skorjanc, Tina</creatorcontrib><creatorcontrib>Erkal, Turan Selman</creatorcontrib><creatorcontrib>Ali, Liaqat</creatorcontrib><creatorcontrib>Raya, Jesus</creatorcontrib><creatorcontrib>Asfari, Zouhair</creatorcontrib><creatorcontrib>Olson, Mark A</creatorcontrib><creatorcontrib>Kirmizialtin, Serdal</creatorcontrib><creatorcontrib>Yazaydin, A. Ozgur</creatorcontrib><creatorcontrib>Trabolsi, Ali</creatorcontrib><title>Rapid and Efficient Removal of Perfluorooctanoic Acid from Water with Fluorine-Rich Calixarene-Based Porous Polymers</title><title>ACS applied materials & interfaces</title><addtitle>ACS Appl. Mater. Interfaces</addtitle><description>On account of its nonbiodegradable nature and persistence in the environment, perfluorooctanoic acid (PFOA) accumulates in water resources and poses serious environmental issues in many parts of the world. Here, we present the development of two fluorine-rich calix[4]arene-based porous polymers, FCX4-P and FCX4-BP, and demonstrate their utility for the efficient removal of PFOA from water. These materials featured Brunauer–Emmett–Teller (BET) surface areas of up to 450 m2 g–1, which is slightly lower than their nonfluorinated counterparts (up to 596 m2 g–1). FCX4-P removes PFOA at environmentally relevant concentrations with a high rate constant of 3.80 g mg–1 h–1 and reached an exceptional maximum PFOA uptake capacity of 188.7 mg g–1. In addition, it could be regenerated by simple methanol wash and reused without a significant decrease in performance.</description><subject>Applications of Polymer, Composite, and Coating Materials</subject><issn>1944-8244</issn><issn>1944-8252</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp1kMtLAzEQxoMoWKtXzzmKsDWvffRYS6tCwVIUj2E2m9CU3U1NdtX-96Zs8eZpXr_5mPkQuqVkQgmjD6ACNHZCFOWCkDM0olMhkoKl7PwvF-ISXYWwIyTjjKQj1G1gbysMbYUXxlhlddvhjW7cF9TYGbzW3tS9886pDlpnFZ6pyBvvGvwBnfb423ZbvDwyttXJxqotnkNtf8DrWD9C0BVeR4E-xFAfGu3DNbowUAd9c4pj9L5cvM2fk9Xr08t8tkqAi7xLMlCiJBmBvNS6yEVKBEtzw6FSkE8zzoFVJTVTQk1FMlYU3BAoWcrzkhUmzsfobtDde_fZ69DJxgal6xpaHe-RTPC8EFRkRUQnA6q8C8FrI_feNuAPkhJ5tFcO9sqTvXHhfliIfblzvW_jJ__Bv1y8fb0</recordid><startdate>20200923</startdate><enddate>20200923</enddate><creator>Shetty, Dinesh</creator><creator>Jahović, Ilma</creator><creator>Skorjanc, Tina</creator><creator>Erkal, Turan Selman</creator><creator>Ali, Liaqat</creator><creator>Raya, Jesus</creator><creator>Asfari, Zouhair</creator><creator>Olson, Mark A</creator><creator>Kirmizialtin, Serdal</creator><creator>Yazaydin, A. Ozgur</creator><creator>Trabolsi, Ali</creator><general>American Chemical Society</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-7494-7887</orcidid><orcidid>https://orcid.org/0000-0001-8380-5725</orcidid><orcidid>https://orcid.org/0000-0003-0398-5063</orcidid><orcidid>https://orcid.org/0000-0001-8562-723X</orcidid></search><sort><creationdate>20200923</creationdate><title>Rapid and Efficient Removal of Perfluorooctanoic Acid from Water with Fluorine-Rich Calixarene-Based Porous Polymers</title><author>Shetty, Dinesh ; Jahović, Ilma ; Skorjanc, Tina ; Erkal, Turan Selman ; Ali, Liaqat ; Raya, Jesus ; Asfari, Zouhair ; Olson, Mark A ; Kirmizialtin, Serdal ; Yazaydin, A. Ozgur ; Trabolsi, Ali</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a347t-6ac4b060a7bee874504257f3adca79633a2db1f901fd062883f0ab2537b28f633</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Applications of Polymer, Composite, and Coating Materials</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shetty, Dinesh</creatorcontrib><creatorcontrib>Jahović, Ilma</creatorcontrib><creatorcontrib>Skorjanc, Tina</creatorcontrib><creatorcontrib>Erkal, Turan Selman</creatorcontrib><creatorcontrib>Ali, Liaqat</creatorcontrib><creatorcontrib>Raya, Jesus</creatorcontrib><creatorcontrib>Asfari, Zouhair</creatorcontrib><creatorcontrib>Olson, Mark A</creatorcontrib><creatorcontrib>Kirmizialtin, Serdal</creatorcontrib><creatorcontrib>Yazaydin, A. Ozgur</creatorcontrib><creatorcontrib>Trabolsi, Ali</creatorcontrib><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>ACS applied materials & interfaces</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shetty, Dinesh</au><au>Jahović, Ilma</au><au>Skorjanc, Tina</au><au>Erkal, Turan Selman</au><au>Ali, Liaqat</au><au>Raya, Jesus</au><au>Asfari, Zouhair</au><au>Olson, Mark A</au><au>Kirmizialtin, Serdal</au><au>Yazaydin, A. Ozgur</au><au>Trabolsi, Ali</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Rapid and Efficient Removal of Perfluorooctanoic Acid from Water with Fluorine-Rich Calixarene-Based Porous Polymers</atitle><jtitle>ACS applied materials & interfaces</jtitle><addtitle>ACS Appl. Mater. Interfaces</addtitle><date>2020-09-23</date><risdate>2020</risdate><volume>12</volume><issue>38</issue><spage>43160</spage><epage>43166</epage><pages>43160-43166</pages><issn>1944-8244</issn><eissn>1944-8252</eissn><abstract>On account of its nonbiodegradable nature and persistence in the environment, perfluorooctanoic acid (PFOA) accumulates in water resources and poses serious environmental issues in many parts of the world. Here, we present the development of two fluorine-rich calix[4]arene-based porous polymers, FCX4-P and FCX4-BP, and demonstrate their utility for the efficient removal of PFOA from water. These materials featured Brunauer–Emmett–Teller (BET) surface areas of up to 450 m2 g–1, which is slightly lower than their nonfluorinated counterparts (up to 596 m2 g–1). FCX4-P removes PFOA at environmentally relevant concentrations with a high rate constant of 3.80 g mg–1 h–1 and reached an exceptional maximum PFOA uptake capacity of 188.7 mg g–1. In addition, it could be regenerated by simple methanol wash and reused without a significant decrease in performance.</abstract><pub>American Chemical Society</pub><doi>10.1021/acsami.0c13400</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0001-7494-7887</orcidid><orcidid>https://orcid.org/0000-0001-8380-5725</orcidid><orcidid>https://orcid.org/0000-0003-0398-5063</orcidid><orcidid>https://orcid.org/0000-0001-8562-723X</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1944-8244 |
| ispartof | ACS applied materials & interfaces, 2020-09, Vol.12 (38), p.43160-43166 |
| issn | 1944-8244 1944-8252 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_2437841468 |
| source | ACS Publications |
| subjects | Applications of Polymer, Composite, and Coating Materials |
| title | Rapid and Efficient Removal of Perfluorooctanoic Acid from Water with Fluorine-Rich Calixarene-Based Porous Polymers |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-06T17%3A10%3A35IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Rapid%20and%20Efficient%20Removal%20of%20Perfluorooctanoic%20Acid%20from%20Water%20with%20Fluorine-Rich%20Calixarene-Based%20Porous%20Polymers&rft.jtitle=ACS%20applied%20materials%20&%20interfaces&rft.au=Shetty,%20Dinesh&rft.date=2020-09-23&rft.volume=12&rft.issue=38&rft.spage=43160&rft.epage=43166&rft.pages=43160-43166&rft.issn=1944-8244&rft.eissn=1944-8252&rft_id=info:doi/10.1021/acsami.0c13400&rft_dat=%3Cproquest_cross%3E2437841468%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2437841468&rft_id=info:pmid/&rfr_iscdi=true |