A chemical reaction model for physical vapor deposition of compound semiconductor films

A model for the physical vapor deposition of compound semiconductor films that describes film growth from component molecular beams is presented. Constitutive relationships are used in the model to account for incomplete adsorption from the incident molecular beams, emission of adsorbed components i...

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Veröffentlicht in:AIChE journal 1987-05, Vol.33 (5), p.711-721
Hauptverfasser: Jackson, S. C., Baron, B. N., Rocheleau, R. E., Russell, T. W. F.
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container_end_page 721
container_issue 5
container_start_page 711
container_title AIChE journal
container_volume 33
creator Jackson, S. C.
Baron, B. N.
Rocheleau, R. E.
Russell, T. W. F.
description A model for the physical vapor deposition of compound semiconductor films that describes film growth from component molecular beams is presented. Constitutive relationships are used in the model to account for incomplete adsorption from the incident molecular beams, emission of adsorbed components into vacuum, and surface reactions of the elemental species. The model predicts film composition and growth rate as a function of incident fluxes and substrate temperature. It is applicable for important binary and ternary alloy semiconductors including the II‐VI and III‐V compounds over the range of deposition conditions yielding both stoichiometric and two‐phase films. In this paper the model equations and the behavior predicted by the model are described for a number of material systems including (CdHg)Te, (CdZn)S, and CuInSe2.
doi_str_mv 10.1002/aic.690330503
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source Wiley Online Library Journals Frontfile Complete
subjects Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Physics
Surfaces and interfaces
thin films and whiskers (structure and nonelectronic properties)
Thin film structure and morphology
title A chemical reaction model for physical vapor deposition of compound semiconductor films
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