Eosin Y as a high-efficient photooxidase mimic for colorimetric detection of sodium azide
The reported fluorescent dye–based artificial light–responsive oxidase mimics are suffering from their low catalytic efficiency. To overcome the limitation, we report the photooxidase-mimicking activity of Eosin Y which can catalyze the oxidation of various chromogenic substrates such as 3,3′,5,5′-t...
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| Veröffentlicht in: | Analytical and bioanalytical chemistry 2020-11, Vol.412 (27), p.7595-7602 |
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| creator | Wang, Junren Yu, Haili He, Yi |
| description | The reported fluorescent dye–based artificial light–responsive oxidase mimics are suffering from their low catalytic efficiency. To overcome the limitation, we report the photooxidase-mimicking activity of Eosin Y which can catalyze the oxidation of various chromogenic substrates such as 3,3′,5,5′-tetramethylbenzydine (TMB), 2,2′-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) diammonium salt (ABTS), 3,3′-diaminobenzidine (DAB), and o-phenylenediamine (OPD) by dissolved oxygen. The photooxidase-like activity of Eosin Y is highly efficient for TMB substrate, and its catalytic efficiency is higher than that of the reported fluorescein (130 fold) and 9-mesityl-10-methylacridinium ion (7.7-fold) mimetic photooxidase. Moreover, the photosensitized Eosin Y-TMB chromogenic system is utilized for colorimetric detection of highly toxic and explosive sodium azide (NaN
3
) in a linear range from 5 to 500 μM with a limit of detection of 3.5 μM. The resulting colorimetric assay is selective and applied to determine NaN
3
in real lake water samples. |
| doi_str_mv | 10.1007/s00216-020-02895-z |
| format | Article |
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3
) in a linear range from 5 to 500 μM with a limit of detection of 3.5 μM. The resulting colorimetric assay is selective and applied to determine NaN
3
in real lake water samples.</description><identifier>ISSN: 1618-2642</identifier><identifier>EISSN: 1618-2650</identifier><identifier>DOI: 10.1007/s00216-020-02895-z</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Analytical Chemistry ; Biochemistry ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Colorimetry ; Dissolved oxygen ; Explosives ; Explosives detection ; Fluorescein ; Fluorescent dyes ; Fluorescent indicators ; Food Science ; Laboratory Medicine ; Mimicry ; Monitoring/Environmental Analysis ; o-Phenylenediamine ; Oxidases ; Oxidation ; Phenylenediamine ; Research Paper ; Sodium ; Sodium azide ; Sodium azides ; Substrates ; Sulfonic acid ; Water analysis ; Water sampling</subject><ispartof>Analytical and bioanalytical chemistry, 2020-11, Vol.412 (27), p.7595-7602</ispartof><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2020</rights><rights>COPYRIGHT 2020 Springer</rights><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2020.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c472t-16c30e4dbb4cd1ad78ff074f2448c67e244aeff2b957731906e817d20a8f1f3b3</citedby><cites>FETCH-LOGICAL-c472t-16c30e4dbb4cd1ad78ff074f2448c67e244aeff2b957731906e817d20a8f1f3b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00216-020-02895-z$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00216-020-02895-z$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,777,781,27905,27906,41469,42538,51300</link.rule.ids></links><search><creatorcontrib>Wang, Junren</creatorcontrib><creatorcontrib>Yu, Haili</creatorcontrib><creatorcontrib>He, Yi</creatorcontrib><title>Eosin Y as a high-efficient photooxidase mimic for colorimetric detection of sodium azide</title><title>Analytical and bioanalytical chemistry</title><addtitle>Anal Bioanal Chem</addtitle><description>The reported fluorescent dye–based artificial light–responsive oxidase mimics are suffering from their low catalytic efficiency. To overcome the limitation, we report the photooxidase-mimicking activity of Eosin Y which can catalyze the oxidation of various chromogenic substrates such as 3,3′,5,5′-tetramethylbenzydine (TMB), 2,2′-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) diammonium salt (ABTS), 3,3′-diaminobenzidine (DAB), and o-phenylenediamine (OPD) by dissolved oxygen. The photooxidase-like activity of Eosin Y is highly efficient for TMB substrate, and its catalytic efficiency is higher than that of the reported fluorescein (130 fold) and 9-mesityl-10-methylacridinium ion (7.7-fold) mimetic photooxidase. Moreover, the photosensitized Eosin Y-TMB chromogenic system is utilized for colorimetric detection of highly toxic and explosive sodium azide (NaN
3
) in a linear range from 5 to 500 μM with a limit of detection of 3.5 μM. The resulting colorimetric assay is selective and applied to determine NaN
3
in real lake water samples.</description><subject>Analytical Chemistry</subject><subject>Biochemistry</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Colorimetry</subject><subject>Dissolved oxygen</subject><subject>Explosives</subject><subject>Explosives detection</subject><subject>Fluorescein</subject><subject>Fluorescent dyes</subject><subject>Fluorescent indicators</subject><subject>Food Science</subject><subject>Laboratory Medicine</subject><subject>Mimicry</subject><subject>Monitoring/Environmental Analysis</subject><subject>o-Phenylenediamine</subject><subject>Oxidases</subject><subject>Oxidation</subject><subject>Phenylenediamine</subject><subject>Research Paper</subject><subject>Sodium</subject><subject>Sodium azide</subject><subject>Sodium azides</subject><subject>Substrates</subject><subject>Sulfonic acid</subject><subject>Water analysis</subject><subject>Water 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Y as a high-efficient photooxidase mimic for colorimetric detection of sodium azide</title><author>Wang, Junren ; Yu, Haili ; He, Yi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c472t-16c30e4dbb4cd1ad78ff074f2448c67e244aeff2b957731906e817d20a8f1f3b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Analytical Chemistry</topic><topic>Biochemistry</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Colorimetry</topic><topic>Dissolved oxygen</topic><topic>Explosives</topic><topic>Explosives detection</topic><topic>Fluorescein</topic><topic>Fluorescent dyes</topic><topic>Fluorescent indicators</topic><topic>Food Science</topic><topic>Laboratory Medicine</topic><topic>Mimicry</topic><topic>Monitoring/Environmental Analysis</topic><topic>o-Phenylenediamine</topic><topic>Oxidases</topic><topic>Oxidation</topic><topic>Phenylenediamine</topic><topic>Research Paper</topic><topic>Sodium</topic><topic>Sodium azide</topic><topic>Sodium azides</topic><topic>Substrates</topic><topic>Sulfonic acid</topic><topic>Water analysis</topic><topic>Water sampling</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Junren</creatorcontrib><creatorcontrib>Yu, Haili</creatorcontrib><creatorcontrib>He, Yi</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials 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USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>MEDLINE - Academic</collection><jtitle>Analytical and bioanalytical chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Junren</au><au>Yu, Haili</au><au>He, Yi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Eosin Y as a high-efficient photooxidase mimic for colorimetric detection of sodium azide</atitle><jtitle>Analytical and bioanalytical chemistry</jtitle><stitle>Anal Bioanal Chem</stitle><date>2020-11-01</date><risdate>2020</risdate><volume>412</volume><issue>27</issue><spage>7595</spage><epage>7602</epage><pages>7595-7602</pages><issn>1618-2642</issn><eissn>1618-2650</eissn><abstract>The reported fluorescent dye–based artificial light–responsive oxidase mimics are suffering from their low catalytic efficiency. To overcome the limitation, we report the photooxidase-mimicking activity of Eosin Y which can catalyze the oxidation of various chromogenic substrates such as 3,3′,5,5′-tetramethylbenzydine (TMB), 2,2′-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) diammonium salt (ABTS), 3,3′-diaminobenzidine (DAB), and o-phenylenediamine (OPD) by dissolved oxygen. The photooxidase-like activity of Eosin Y is highly efficient for TMB substrate, and its catalytic efficiency is higher than that of the reported fluorescein (130 fold) and 9-mesityl-10-methylacridinium ion (7.7-fold) mimetic photooxidase. Moreover, the photosensitized Eosin Y-TMB chromogenic system is utilized for colorimetric detection of highly toxic and explosive sodium azide (NaN
3
) in a linear range from 5 to 500 μM with a limit of detection of 3.5 μM. The resulting colorimetric assay is selective and applied to determine NaN
3
in real lake water samples.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00216-020-02895-z</doi><tpages>8</tpages><oa>free_for_read</oa></addata></record> |
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| subjects | Analytical Chemistry Biochemistry Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Colorimetry Dissolved oxygen Explosives Explosives detection Fluorescein Fluorescent dyes Fluorescent indicators Food Science Laboratory Medicine Mimicry Monitoring/Environmental Analysis o-Phenylenediamine Oxidases Oxidation Phenylenediamine Research Paper Sodium Sodium azide Sodium azides Substrates Sulfonic acid Water analysis Water sampling |
| title | Eosin Y as a high-efficient photooxidase mimic for colorimetric detection of sodium azide |
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