Redispersion of cobalt particles supported on titanium dioxide

The particle size of cobalt in a Co/TiO sub 2 catalyst increased with increasing reduction temperature up to 600 deg C. At 700 deg C, where the phase transformation of TiO sub 2 from anatase to rutile occurred, the cobalt particles redispersed to individual crystallites. This redispersion has been c...

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Veröffentlicht in:J. Chem. Soc., Faraday Trans. I Faraday Trans. I, 1984-01, Vol.80 (4), p.803-811
Hauptverfasser: TAKASAKI, S, SUZUKI, H, TAKAHASHI, K, TANABE, S, UENO, A, KOTERA, Y
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container_issue 4
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container_title J. Chem. Soc., Faraday Trans. I
container_volume 80
creator TAKASAKI, S
SUZUKI, H
TAKAHASHI, K
TANABE, S
UENO, A
KOTERA, Y
description The particle size of cobalt in a Co/TiO sub 2 catalyst increased with increasing reduction temperature up to 600 deg C. At 700 deg C, where the phase transformation of TiO sub 2 from anatase to rutile occurred, the cobalt particles redispersed to individual crystallites. This redispersion has been confirmed by measuring the specific activity of the cobalt catalyst for the hydrogenation of propene. The relation between the phase transformation of TiO sub 2 and the redispersion of cobalt has been studied kinetically using high-temperature X-ray diffraction spectroscopy. 12 ref.--AA
doi_str_mv 10.1039/f19848000803
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source Royal Society of Chemistry Journals Archive (1841-2007); Alma/SFX Local Collection
subjects Catalysis
Catalysts: preparations and properties
Catalytic reactions
Chemistry
Exact sciences and technology
General and physical chemistry
General. Nomenclature, chemical documentation, computer chemistry
Theory of reactions, general kinetics
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
title Redispersion of cobalt particles supported on titanium dioxide
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