PANI/BaFe12O19@Halloysite ternary composites as novel microwave absorbent

[Display omitted] A three-phase PANI/BaFe12O19@Hal heterostructure was designed and fabricated in this paper as efficient lightweight electromagnetic wave absorbing material through the combination of citrate assisted sol–gel self-propagating combustion and in-situ oxidative polymerization of anilin...

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Veröffentlicht in:Journal of colloid and interface science 2021-01, Vol.582, p.137-148
Hauptverfasser: Chen, Zihao, Mu, Dawei, Liu, Tianhao, He, Zilong, Zhang, Yi, Yang, Huaming, Ouyang, Jing
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container_end_page 148
container_issue
container_start_page 137
container_title Journal of colloid and interface science
container_volume 582
creator Chen, Zihao
Mu, Dawei
Liu, Tianhao
He, Zilong
Zhang, Yi
Yang, Huaming
Ouyang, Jing
description [Display omitted] A three-phase PANI/BaFe12O19@Hal heterostructure was designed and fabricated in this paper as efficient lightweight electromagnetic wave absorbing material through the combination of citrate assisted sol–gel self-propagating combustion and in-situ oxidative polymerization of aniline. In addition, the effects of the weight ratio of different PANI to BF@Hal on the microwave absorption properties of the materials were studied. The results show that when the weight ratio of PANI is 40%, the material has the best microwave absorption performance. The frequency bandwidth below −5 dB reached 9.60 GHz and the minimum absorption peak at 11.92 GHz was −14.77 dB. The combination of the PANI and BF@Hal nanosheets take advantage of the interfacial polarization, natural resonance, dielectric polarization and trapping of EM waves by internal reflection in PANI/BaFe12O19@Hal. Taking advantage of the unique microscopic morphology and interface characteristics, halloysite was introduced to improve the microwave absorption performance and enrich the absorbing mechanism of the composite materials. This work may provide a reliable candidate for the synthesis of electromagnetic attenuation materials with fairly good performances.
doi_str_mv 10.1016/j.jcis.2020.08.006
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subjects Barium ferrite
Halloysite
Magnetism
Microwave absorbing property
Polyaniline
title PANI/BaFe12O19@Halloysite ternary composites as novel microwave absorbent
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