Copper‐Catalyzed Aqueous N−O Bond Cleavage of 2‐Oxa‐3‐Azabicyclo Compounds to Cyclic cis‐1,4‐Amino Alcohols

The N−O bond cleavage of 2‐oxa‐3‐azabicyclo substrates, which are readily prepared by the hetero Diels‐Alder reaction between nitroso dienophiles and cyclic 1,3‐dienes, was effectively catalyzed by heterogeneous copper‐on‐carbon (Cu/C) under aqueous conditions to give the corresponding cyclic cis‐1,...

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Veröffentlicht in:	ChemSusChem 2020-11, Vol.13 (21), p.5632-5637
Hauptverfasser:	Yasukawa, Naoki, Miki, Yuya, Kuwata, Marina, Sajiki, Hironao, Sawama, Yoshinari
Format:	Artikel
Sprache:	eng
Schlagworte:	Alcohols aqueous solutions Carbon Cleavage Copper Dienes heterogeneous catalysis N−O bond cleavage one-pot synthesis Ruthenium Selectivity Substrates
Online-Zugang:	Volltext
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