Effect of Ligand Chelation and Sacrificial Oxidant on the Integrity of Triazole-Based Carbene Iridium Water Oxidation Catalysts

We report the effect of replacing the pyridine group in the chelating trz Ir–water oxidation catalysts by a benzoxazole and a thiazole moiety. We have also evaluated if the presence of bidentate ligands is crucial for high activities and to avoid the decomposition into undesired heterogeneous layers...

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Veröffentlicht in:	Inorganic chemistry 2020-09, Vol.59 (17), p.12337-12347
Hauptverfasser:	Mazloomi, Zahra, Margalef, Jessica, Gil-Sepulcre, Marcos, Romero, Nuria, Albrecht, Martin, Llobet, Antoni, Sala, Xavier, Pàmies, Oscar, Diéguez, Montserrat
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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