anti-Hydroarylation of Activated Internal Alkynes: Merging Pd and Energy Transfer Catalysis

A general catalytic anti-hydroarylation of electron-deficient internal alkynes compatible with both electron-poor and electron-rich aryl reagents is reported. This selectivity is achieved through a sequential syn-carbopalladation of the alkyne by an Ar–Pd species, followed by a tandem, Ir-photocatal...

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Veröffentlicht in:	Organic letters 2020-08, Vol.22 (16), p.6473-6478
Hauptverfasser:	Corpas, Javier, Mauleón, Pablo, Gómez Arrayás, Ramón, Carretero, Juan C
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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