Dichotomous Si–H Bond Activation by Alkoxide and Alcohol in Base-Catalyzed Dehydrocoupling of Silanes

The activation of silanes in dehydrogenative coupling with alcohols under general base catalysis was studied experimentally (using multinuclear NMR, IR, and UV–visible spectroscopies) and computationally (at DFT M06/6-311++G­(d,p) theory level) on the example of Ph4‑n SiH n (n = 1–3) interaction wit...

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Veröffentlicht in:	Inorganic chemistry 2020-09, Vol.59 (17), p.12240-12251
Hauptverfasser:	Voronova, Evgenia D, Golub, Igor E, Pavlov, Alexander, Belkova, Natalia V, Filippov, Oleg A, Epstein, Lina M, Shubina, Elena S
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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