Strong Magnetic Anisotropy of Epitaxial PrVO3 Thin Films on SrTiO3 Substrates with Different Orientations
We have probed the structural and magnetic properties of PrVO3 (PVO) thin films grown on the (001)-, (110)-, and (111)-oriented SrTiO3 (STO) substrates. By changing the substrate orientation, the film out-of-plane orientation can be tuned to [110], [100]/[010], and [011]/[311], with different in-pla...
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Veröffentlicht in: | ACS applied materials & interfaces 2020-08, Vol.12 (31), p.35606-35613 |
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creator | Kumar, Deepak David, Adrian Fouchet, Arnaud Pautrat, Alain Boullay, Philippe Jung, Chang Uk Prellier, Wilfrid |
description | We have probed the structural and magnetic properties of PrVO3 (PVO) thin films grown on the (001)-, (110)-, and (111)-oriented SrTiO3 (STO) substrates. By changing the substrate orientation, the film out-of-plane orientation can be tuned to [110], [100]/[010], and [011]/[311], with different in-plane crystallographic variants. Accommodation of these variants on the different substrates implies different strain states, which have direct influence on the magnetic properties of PVO films. The magnetic moment of PVO films radically enhances from 0.4 μB/f.u. for STO(001) to 2.3 μB/f.u. for STO(111). While films on the (001)-oriented STO substrate display out-of-plane anisotropy, an in-plane anisotropy is observed for films grown on the (110)- and (111)-oriented STO substrates. In addition, a strong uniaxial magnetic anisotropy is also extracted for a partially relaxed film on the (110)-oriented STO substrate. Such findings can help oxide community for the better understanding of magnetic anisotropy in vanadate thin films, a subject that still suffer from significant lack of scientific investigations. |
doi_str_mv | 10.1021/acsami.0c07794 |
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By changing the substrate orientation, the film out-of-plane orientation can be tuned to [110], [100]/[010], and [011]/[311], with different in-plane crystallographic variants. Accommodation of these variants on the different substrates implies different strain states, which have direct influence on the magnetic properties of PVO films. The magnetic moment of PVO films radically enhances from 0.4 μB/f.u. for STO(001) to 2.3 μB/f.u. for STO(111). While films on the (001)-oriented STO substrate display out-of-plane anisotropy, an in-plane anisotropy is observed for films grown on the (110)- and (111)-oriented STO substrates. In addition, a strong uniaxial magnetic anisotropy is also extracted for a partially relaxed film on the (110)-oriented STO substrate. 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Such findings can help oxide community for the better understanding of magnetic anisotropy in vanadate thin films, a subject that still suffer from significant lack of scientific investigations.</description><subject>Surfaces, Interfaces, and Applications</subject><issn>1944-8244</issn><issn>1944-8252</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNo9kE1LAzEURYMoWKtb11mKMDVfM5ksS21VqFRodRvSTKZNmSY1yaD-eyMtru7jcrg8DgC3GI0wIvhB6aj2doQ04lywMzDAgrGiJiU5_78ZuwRXMe4QqihB5QDYZQrebeCr2jiTrIZjZ6PP3eEH-hZODzapb6s6-BY-FhSuttbBme32EXoHl2Flc7ns1zEFlUyEXzZt4aNtWxOMS3ARbA6VrHfxGly0qovm5pRD8D6bribPxXzx9DIZzwuFBU1FrVqOMOVCM0w4r2pOdKMqxGtiTFWLtmoQX1dNjUm5RjrjglKGMNOk4YgYOgR3x91D8J-9iUnubdSm65Qzvo-SMFpigUsmMnp_RLM6ufN9cPkxiZH88ymPPuXJJ_0FtuFpdA</recordid><startdate>20200805</startdate><enddate>20200805</enddate><creator>Kumar, Deepak</creator><creator>David, Adrian</creator><creator>Fouchet, Arnaud</creator><creator>Pautrat, Alain</creator><creator>Boullay, Philippe</creator><creator>Jung, Chang Uk</creator><creator>Prellier, Wilfrid</creator><general>American Chemical Society</general><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-1492-2837</orcidid><orcidid>https://orcid.org/0000-0002-3604-4756</orcidid><orcidid>https://orcid.org/0000-0002-2867-8986</orcidid></search><sort><creationdate>20200805</creationdate><title>Strong Magnetic Anisotropy of Epitaxial PrVO3 Thin Films on SrTiO3 Substrates with Different Orientations</title><author>Kumar, Deepak ; David, Adrian ; Fouchet, Arnaud ; Pautrat, Alain ; Boullay, Philippe ; Jung, Chang Uk ; Prellier, Wilfrid</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a193t-8af701379c412776872cda60782ee689f6d07b6d8125b0c8af9334014c2d702e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Surfaces, Interfaces, and Applications</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kumar, Deepak</creatorcontrib><creatorcontrib>David, Adrian</creatorcontrib><creatorcontrib>Fouchet, Arnaud</creatorcontrib><creatorcontrib>Pautrat, Alain</creatorcontrib><creatorcontrib>Boullay, Philippe</creatorcontrib><creatorcontrib>Jung, Chang Uk</creatorcontrib><creatorcontrib>Prellier, Wilfrid</creatorcontrib><collection>MEDLINE - Academic</collection><jtitle>ACS applied materials & interfaces</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kumar, Deepak</au><au>David, Adrian</au><au>Fouchet, Arnaud</au><au>Pautrat, Alain</au><au>Boullay, Philippe</au><au>Jung, Chang Uk</au><au>Prellier, Wilfrid</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Strong Magnetic Anisotropy of Epitaxial PrVO3 Thin Films on SrTiO3 Substrates with Different Orientations</atitle><jtitle>ACS applied materials & interfaces</jtitle><addtitle>ACS Appl. Mater. Interfaces</addtitle><date>2020-08-05</date><risdate>2020</risdate><volume>12</volume><issue>31</issue><spage>35606</spage><epage>35613</epage><pages>35606-35613</pages><issn>1944-8244</issn><eissn>1944-8252</eissn><abstract>We have probed the structural and magnetic properties of PrVO3 (PVO) thin films grown on the (001)-, (110)-, and (111)-oriented SrTiO3 (STO) substrates. By changing the substrate orientation, the film out-of-plane orientation can be tuned to [110], [100]/[010], and [011]/[311], with different in-plane crystallographic variants. Accommodation of these variants on the different substrates implies different strain states, which have direct influence on the magnetic properties of PVO films. The magnetic moment of PVO films radically enhances from 0.4 μB/f.u. for STO(001) to 2.3 μB/f.u. for STO(111). While films on the (001)-oriented STO substrate display out-of-plane anisotropy, an in-plane anisotropy is observed for films grown on the (110)- and (111)-oriented STO substrates. In addition, a strong uniaxial magnetic anisotropy is also extracted for a partially relaxed film on the (110)-oriented STO substrate. Such findings can help oxide community for the better understanding of magnetic anisotropy in vanadate thin films, a subject that still suffer from significant lack of scientific investigations.</abstract><pub>American Chemical Society</pub><doi>10.1021/acsami.0c07794</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-1492-2837</orcidid><orcidid>https://orcid.org/0000-0002-3604-4756</orcidid><orcidid>https://orcid.org/0000-0002-2867-8986</orcidid><oa>free_for_read</oa></addata></record> |
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title | Strong Magnetic Anisotropy of Epitaxial PrVO3 Thin Films on SrTiO3 Substrates with Different Orientations |
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