Role of Molecular Structure in the Production of Water-Soluble Species by Photo-oxidation of Petroleum

Asphaltenes are high-boiling and recalcitrant compounds that are generally minor components of crude oil (∼0.1–15.0 wt %) but dominate the composition of heavily weathered spilled petroleum. These solid residues exhibit a high structural complexity, comprised of polycyclic aromatic hydrocarbons (PAH...

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Veröffentlicht in:	Environmental science & technology 2020-08, Vol.54 (16), p.9968-9979
Hauptverfasser:	Chacón-Patiño, Martha L, Niles, Sydney F, Marshall, Alan G, Hendrickson, Christopher L, Rodgers, Ryan P
Format:	Artikel
Sprache:	eng
Schlagworte:	Addition polymerization Archipelagoes Aromaticity Artificial seawater Asphaltenes Boiling Carbon Chemical analysis Chemical composition Chemical fingerprinting Contaminants in Aquatic and Terrestrial Environments Crude oil Cyclotron resonance Dissolved organic matter Distillation Distilled water Fossil fuels Fourier transforms Hydrocarbons Ions Mass spectrometry Mass spectroscopy Molecular structure Oil spills Oxidation Petroleum Petroleum residues Photolysis Photooxidation Photopolymerization Polycyclic aromatic hydrocarbons Polymerization Seawater Solar simulators Species Water analysis Water chemistry
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